{"id":"W2109441728","doi":"10.1002/anie.201102453","title":"3,7‐Diazadibenzophosphole Oxide: A Phosphorus‐Bridged Viologen Analogue with Significantly Lowered Reduction Threshold","year":2011,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":114,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Viologen; Reduction (mathematics); Chemistry; Phosphorus; Bridge (graph theory); Combinatorial chemistry; Computer science; Information retrieval; Photochemistry; Mathematics; Organic chemistry; Medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001250767,0.0003278351,0.0002638986,0.0001032586,0.0001314818,0.00005644859,0.0004522832,0.0002919756,0.004235574],"category_scores_gemma":[0.0001688021,0.0003036743,0.0001717215,0.0002398115,0.0002528254,0.0004224153,0.00006122747,0.0005090169,0.0001319038],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004343538,"about_ca_system_score_gemma":0.00009576489,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004418083,"about_ca_topic_score_gemma":0.00001795585,"domain_scores_codex":[0.9979152,0.000008501949,0.0004476632,0.0006517976,0.0005895098,0.0003873319],"domain_scores_gemma":[0.9986678,0.00006965773,0.0002739826,0.0004210312,0.0003172053,0.0002503422],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005658006,0.0003914326,0.0006303481,0.00001897452,0.0002212635,0.00004948911,0.0001960985,0.000012581,0.978026,0.0003102784,0.01920399,0.0003737282],"study_design_scores_gemma":[0.000879812,0.00005362622,0.001049686,0.000108059,0.00007294535,0.0001170679,0.0002606141,0.0000680104,0.9886128,0.001774701,0.006626712,0.0003760086],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8970472,0.000118251,0.001130646,0.0003222194,0.0008632747,0.0002137097,0.0003714396,0.0003534608,0.09957983],"genre_scores_gemma":[0.9947925,0.0001181332,0.0007256806,0.0001605834,0.0009149397,0.0002404041,0.001653802,0.00005578093,0.001338161],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09824167,"threshold_uncertainty_score":0.9999415,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02373534306833552,"score_gpt":0.2354404959167986,"score_spread":0.2117051528484631,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}