{"id":"W2109575041","doi":"10.1002/chem.201303699","title":"Stereoselective Lewis Acid Mediated (3+2) Cycloadditions of <i>N</i>‐H‐ and <i>N</i>‐Sulfonylaziridines with Heterocumulenes","year":2014,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":94,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; National Institute of General Medical Sciences; U.S. Public Health Service; California Institute of Technology; Natural Sciences and Engineering Research Council of Canada; Amgen; National Cancer Institute; National Institutes of Health; National Science Foundation","keywords":"Stereoselectivity; Cycloaddition; Chemistry; Sulfonyl; Derivatization; Context (archaeology); Lewis acids and bases; Aryl; Alkyl; Stereochemistry; Combinatorial chemistry; Organic chemistry; Catalysis; High-performance liquid chromatography","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002166973,0.0005583261,0.0001997928,0.000188667,0.0001670808,0.0001954319,0.0003554901,0.0002087682,0.002149121],"category_scores_gemma":[0.0001522797,0.0001870133,0.0002124615,0.0001528661,0.0002599348,0.00025842,0.0002451263,0.0003264255,0.0007014902],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003092236,"about_ca_system_score_gemma":0.0003251133,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005697593,"about_ca_topic_score_gemma":0.002269964,"domain_scores_codex":[0.9998549,0.00002467574,0.00001038584,0.00002675966,0.00003282,0.00005049564],"domain_scores_gemma":[0.9999287,0.00001452426,0.00002410393,0.00001201088,0.000008158886,0.00001253522],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001095455,0.00003002399,0.0001238447,0.00006028511,0.000007259968,0.0001568984,0.0000576257,0.0002578337,0.9936038,0.001105858,0.0002188252,0.004268168],"study_design_scores_gemma":[0.000009975832,0.0001087986,0.0002709307,0.000001449017,0.000004094585,0.00008810045,0.000009067805,0.0002156516,0.9978855,0.00004200411,0.001359614,0.000004807656],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9587262,0.0007398587,0.01471537,0.0001168256,0.00007087801,0.000120805,0.0003103714,0.000355544,0.02484416],"genre_scores_gemma":[0.9921439,0.0005650033,0.003800507,0.00003846329,0.00001466058,0.00004049351,0.0001654949,0.00003880169,0.003192707],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002149121,"threshold_uncertainty_score":0.007189572,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008408636366549338,"score_gpt":0.1918483306022954,"score_spread":0.1834396942357461,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}