{"id":"W2109949531","doi":"10.1002/anie.201005640","title":"Unusually Strong Binding of Dinitrogen to a Ruthenium Center","year":2010,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Lability; IMes; Ruthenium; Chemistry; Catalysis; Ligand (biochemistry); Transition metal; Center (category theory); Stereochemistry; Photochemistry; Carbene; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001762596,0.0003259463,0.0003105963,0.0001095706,0.0003146374,0.0003821909,0.0006038107,0.0005401037,0.002703595],"category_scores_gemma":[0.000237319,0.0002314453,0.0001044511,0.00009248505,0.0002705026,0.0002375284,0.0005876584,0.0003381328,0.0004727503],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000505007,"about_ca_system_score_gemma":0.0001590626,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001827982,"about_ca_topic_score_gemma":0.003716075,"domain_scores_codex":[0.9997239,0.0000323817,0.000006319912,0.00007102339,0.00007099163,0.00009541723],"domain_scores_gemma":[0.9999269,0.0000188355,0.00001560276,0.00001216283,0.000008604651,0.00001790919],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002254137,0.00002565748,0.0006123387,0.0001442895,0.00002472315,0.0002759428,0.0000811162,0.0004585394,0.9930571,0.001113902,0.0008368382,0.003144046],"study_design_scores_gemma":[0.00002987,0.0002603888,0.002835589,0.000007723113,0.0000149481,0.0003964183,0.00008749592,0.00241646,0.9896584,0.0002576062,0.004016295,0.00001877585],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895375,0.0004254882,0.001970026,0.0001561404,0.00003060203,0.000008357741,0.00007777655,0.0001179669,0.007676169],"genre_scores_gemma":[0.9984125,0.00005356101,0.0003785962,0.0000408008,0.000003306885,0.00000399385,0.00006521661,0.00001072577,0.001031303],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002703595,"threshold_uncertainty_score":0.009044468,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01003357381743743,"score_gpt":0.2563747202919067,"score_spread":0.2463411464744693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}