{"id":"W2110148683","doi":"10.1039/b311763d","title":"Novel 1,3-dipolar cycloaddition of diazocarbonyl compounds to alkynes catalyzed by InCl3 in water","year":2004,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":99,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Cycloaddition; Catalysis; Intermolecular force; Aryl; Chemistry; Alkyl; Domino; 1,3-Dipolar cycloaddition; Computational chemistry; Medicinal chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001093799,0.0004606788,0.0002594537,0.000159113,0.0001944739,0.0003307482,0.0003221726,0.000268783,0.001126018],"category_scores_gemma":[0.0001023977,0.0002158321,0.0002027854,0.0001454675,0.0002117173,0.0003779372,0.0002638781,0.0004344055,0.0003955577],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002799429,"about_ca_system_score_gemma":0.0001970505,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004317254,"about_ca_topic_score_gemma":0.001259286,"domain_scores_codex":[0.999892,0.00001137746,0.000007179728,0.0000281913,0.00002241164,0.0000388843],"domain_scores_gemma":[0.9999712,0.000005085972,0.00000834348,0.000003310017,0.00000360893,0.000008507886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004189408,0.00002572669,0.00008277603,0.0001336055,0.000007804919,0.0004943921,0.00005955689,0.0002056505,0.991397,0.001060886,0.0001982621,0.006292454],"study_design_scores_gemma":[0.00001032866,0.0001179991,0.0003037008,0.00000451776,0.000007228247,0.000287016,0.00001476301,0.000268914,0.9934365,0.00008467727,0.00545579,0.000008613473],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9493415,0.005527925,0.02181027,0.0002436368,0.0001734498,0.0002353178,0.0003077738,0.0004009035,0.02195919],"genre_scores_gemma":[0.9838786,0.002965811,0.007724201,0.00005365327,0.00002055786,0.0000671489,0.000139136,0.00003008732,0.005120867],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001126018,"threshold_uncertainty_score":0.003766894,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01705677363216386,"score_gpt":0.25398891156663,"score_spread":0.2369321379344662,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}