{"id":"W2110263848","doi":"10.1021/bi062266+","title":"Redox Intermediates in the Catalase Cycle of Catalase-Peroxidases from <i>Synechocystis</i> PCC 6803<i>, Burkholderia pseudomallei</i>, and <i>Mycobacterium tuberculosis</i>","year":2007,"lang":"en","type":"article","venue":"Biochemistry","topic":"Enzyme-mediated dye degradation","field":"Agricultural and Biological Sciences","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Hydrogen peroxide; Catalase; Chemistry; Peroxidase; Burkholderia; Synechocystis; Reaction intermediate; Catalytic cycle; Stereochemistry; Porphyrin; Photochemistry; Biochemistry; Enzyme; Bacteria; Catalysis; Biology; Mutant","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004107988,0.000230523,0.000234704,0.00001606907,0.00008082502,0.00005779014,0.0003856792,0.0002169478,0.00006011668],"category_scores_gemma":[0.0002373363,0.0001015747,0.00007186718,0.0003274116,0.0002067637,0.0001360654,0.0001048155,0.000204984,0.000008871529],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003506621,"about_ca_system_score_gemma":0.00001505556,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001634203,"about_ca_topic_score_gemma":0.0009937412,"domain_scores_codex":[0.9984829,0.00005349893,0.0004354195,0.0004201431,0.0002771473,0.0003309064],"domain_scores_gemma":[0.9988184,0.0006481922,0.000174739,0.0001855186,0.00005518251,0.0001179594],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005263384,0.0001363644,0.01457807,0.00002798605,0.00001127522,0.00002320169,0.000157706,4.412383e-7,0.9814776,0.000003945593,0.0009756961,0.002555036],"study_design_scores_gemma":[0.0003080927,0.00005773025,0.1106698,0.0000859459,0.00002374179,0.00002477671,0.000968116,0.00001283241,0.8869199,0.0000618889,0.0006551432,0.0002120635],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973533,0.0008232641,0.000001624226,0.0005212377,0.000114546,0.0001695488,0.0007084523,0.00004808195,0.0002599974],"genre_scores_gemma":[0.9972255,0.0001724743,0.00008108602,0.0002934903,0.0002993209,0.00001854149,0.001877703,0.000003015654,0.00002891924],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09609177,"threshold_uncertainty_score":0.4142095,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005621524339402962,"score_gpt":0.1985028517803122,"score_spread":0.1928813274409092,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}