{"id":"W2110263848","doi":"10.1021/bi062266+","title":"Redox Intermediates in the Catalase Cycle of Catalase-Peroxidases from <i>Synechocystis</i> PCC 6803<i>, Burkholderia pseudomallei</i>, and <i>Mycobacterium tuberculosis</i>","year":2007,"lang":"en","type":"article","venue":"Biochemistry","topic":"Enzyme-mediated dye degradation","field":"Agricultural and Biological Sciences","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Hydrogen peroxide; Catalase; Chemistry; Peroxidase; Burkholderia; Synechocystis; Reaction intermediate; Catalytic cycle; Stereochemistry; Porphyrin; Photochemistry; Biochemistry; Enzyme; Bacteria; Catalysis; Biology; Mutant","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001776308,0.0003511304,0.0001603199,0.0002332239,0.0001344708,0.0002924761,0.0002385158,0.0002684342,0.0002652781],"category_scores_gemma":[0.0002758834,0.0001999193,0.000207729,0.0002454788,0.0001615127,0.0003474973,0.0001344487,0.000458231,0.0001470733],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004367753,"about_ca_system_score_gemma":0.0002840171,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001452271,"about_ca_topic_score_gemma":0.0009156294,"domain_scores_codex":[0.9998585,0.00002500192,0.00001056953,0.00003762769,0.00003781973,0.00003046175],"domain_scores_gemma":[0.9998428,0.00003465181,0.000037285,0.00001322585,0.00004371965,0.00002826529],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002097505,0.00002639203,0.0009847333,0.00005593419,0.000009482979,0.00007069604,0.00008254964,0.0001830796,0.9957114,0.0002577202,0.0000437539,0.002364433],"study_design_scores_gemma":[0.00001562762,0.0001539885,0.01124094,0.00001121165,0.00002104946,0.0002477352,0.00008457286,0.001412686,0.9850846,0.0003938408,0.001322726,0.00001102043],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910458,0.001643968,0.005835949,0.00005988057,0.00001962035,0.00002385299,0.0003605526,0.0001043705,0.0009060294],"genre_scores_gemma":[0.9956351,0.000370685,0.002748036,0.00002488952,0.000002661539,0.00002171818,0.000644392,0.00001591556,0.0005366353],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001452271,"threshold_uncertainty_score":0.003169,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005621524339402962,"score_gpt":0.1985028517803122,"score_spread":0.1928813274409092,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}