{"id":"W2111759346","doi":"10.1039/c2cc37110c","title":"Racemic marinopyrrole B by total synthesis","year":2012,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Pyrrole; Ring (chemistry); Chemistry; Alkylation; Allylic rearrangement; Stereochemistry; Tsuji–Trost reaction; Total synthesis; Acceptor; Michael reaction; Medicinal chemistry; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001443397,0.0001111553,0.0001874431,0.00002916502,0.0001038972,0.00001217704,0.0003090475,0.0001135887,0.0003289811],"category_scores_gemma":[0.0004572484,0.00008995525,0.00008728043,0.0001538101,0.0001668388,0.00009178703,0.0002863782,0.0003031909,0.0002318067],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006515659,"about_ca_system_score_gemma":0.00001975385,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002219382,"about_ca_topic_score_gemma":3.560966e-7,"domain_scores_codex":[0.9992895,0.00003710883,0.0001860605,0.0001293903,0.000099359,0.0002585492],"domain_scores_gemma":[0.9982968,0.0002252811,0.00004765261,0.00119201,0.00005617661,0.0001820632],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002259264,0.000303151,0.0009319464,0.00001710879,0.00002954466,1.02536e-7,0.00004152528,5.478852e-9,0.952005,0.0002180752,0.03876985,0.007661096],"study_design_scores_gemma":[0.0001334932,0.000007779606,0.0006703438,0.00003145682,0.0000996859,0.00004841208,0.00003442302,0.00001639987,0.8734805,0.00001846997,0.1253358,0.0001232064],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9425003,0.007772701,0.00001455069,0.02306013,0.00008018056,0.0003036059,0.00005593494,0.0001621964,0.02605041],"genre_scores_gemma":[0.9938225,0.0002776258,0.003600931,0.000497918,0.0001259313,0.000008340206,0.00009979225,0.00001722414,0.001549707],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08656596,"threshold_uncertainty_score":0.3668269,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02305501249747199,"score_gpt":0.2741432813403583,"score_spread":0.2510882688428863,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}