{"id":"W2112225100","doi":"10.1021/jacs.5b01352","title":"Metal–Organic Framework Based upon the Synergy of a Brønsted Acid Framework and Lewis Acid Centers as a Highly Efficient Heterogeneous Catalyst for Fixed-Bed Reactions","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":263,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada)","funders":"Division of Materials Research","keywords":"Chemistry; Brønsted–Lowry acid–base theory; Lewis acids and bases; Catalysis; Metal-organic framework; Context (archaeology); Zeolite; Lewis acid catalysis; Combinatorial chemistry; Organic chemistry; Adsorption","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000545377,0.0003046622,0.0007074131,0.00002277345,0.0002240728,0.00006422546,0.0008986872,0.0002555103,0.0000861116],"category_scores_gemma":[0.001860969,0.000187298,0.0009978955,0.0006226454,0.0006495895,0.0000463815,0.0001855587,0.0009362717,0.000002867396],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002494167,"about_ca_system_score_gemma":0.0002164934,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004664701,"about_ca_topic_score_gemma":0.00000140554,"domain_scores_codex":[0.9977672,0.0000841826,0.0008285563,0.0003233533,0.0006148064,0.0003818969],"domain_scores_gemma":[0.995698,0.001192834,0.001673302,0.0008390024,0.0003056483,0.0002912507],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001389673,0.0003054249,0.00007572417,0.00005046958,0.0005591444,8.808974e-7,0.0005096596,0.000223856,0.9963139,0.0001632098,0.0009617321,0.0006969967],"study_design_scores_gemma":[0.0004297867,0.00007077238,0.00001644035,0.0002533585,0.0005422352,0.0000913582,0.001718793,0.001623026,0.9903954,0.001046106,0.003596914,0.000215818],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9793682,0.0008069946,0.01313143,0.006243188,0.0001464579,0.0001755401,0.0000608342,0.00002909456,0.0000383015],"genre_scores_gemma":[0.9842928,0.0001069266,0.01432504,0.0008606649,0.0002891175,0.00003486553,0.00000655083,0.00005456219,0.00002949373],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005918542,"threshold_uncertainty_score":0.7637789,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01353730819973351,"score_gpt":0.2511650682745646,"score_spread":0.2376277600748311,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}