{"id":"W2112701005","doi":"10.1002/adsc.200800542","title":"Nickel‐Catalyzed Synthesis of Phosphonium Salts from Aryl Halides and Triphenylphosphine","year":2008,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":85,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Triphenylphosphine; Phosphonium; Aryl; Halide; Nickel; Catalysis; Organic chemistry; Phenols; Triphenylphosphine oxide; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001663756,0.0005196374,0.0003796729,0.0003252761,0.0003131617,0.00048484,0.0007817441,0.0003379674,0.002238995],"category_scores_gemma":[0.0002244453,0.0003562219,0.0002667003,0.0003711007,0.0001469693,0.0004855421,0.0005589656,0.0005132745,0.002259117],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004187595,"about_ca_system_score_gemma":0.0006336917,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007159051,"about_ca_topic_score_gemma":0.001485414,"domain_scores_codex":[0.9998208,0.00001649324,0.00003364589,0.00002904584,0.00006462324,0.00003545136],"domain_scores_gemma":[0.9999343,0.000005779251,0.00001327077,0.00001028741,0.0000163987,0.00001998793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008508411,0.00003812672,0.0000816534,0.0003911285,0.00002352991,0.0004644945,0.00008788062,0.0005874438,0.9839124,0.002129244,0.000715229,0.01148378],"study_design_scores_gemma":[0.00003327812,0.0001181311,0.0001062168,0.00001475186,0.00002036096,0.0002684951,0.00001349523,0.0008112177,0.9869654,0.0002436155,0.01139271,0.00001228323],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7995548,0.009555632,0.09379706,0.0008639291,0.0008378953,0.000582987,0.00254061,0.003146425,0.08912075],"genre_scores_gemma":[0.9381354,0.006194493,0.03568409,0.0001256494,0.00005359744,0.0002575626,0.001333122,0.0002858539,0.01793034],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002238995,"threshold_uncertainty_score":0.007490158,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01049153544261835,"score_gpt":0.2314846599056505,"score_spread":0.2209931244630322,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}