{"id":"W2112701005","doi":"10.1002/adsc.200800542","title":"Nickel‐Catalyzed Synthesis of Phosphonium Salts from Aryl Halides and Triphenylphosphine","year":2008,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":85,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Triphenylphosphine; Phosphonium; Aryl; Halide; Nickel; Catalysis; Organic chemistry; Phenols; Triphenylphosphine oxide; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000240008,0.0006283036,0.001391957,0.0002328284,0.0004380468,0.00005287321,0.0006250616,0.0003052425,0.001051126],"category_scores_gemma":[0.002890764,0.0006484523,0.0005486093,0.0006811664,0.0007661383,0.000520121,0.0002387045,0.0003287015,0.0001036015],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002268413,"about_ca_system_score_gemma":0.0001460041,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003585984,"about_ca_topic_score_gemma":0.0002646583,"domain_scores_codex":[0.9964228,0.000004130262,0.001119361,0.001175016,0.0006533958,0.0006253242],"domain_scores_gemma":[0.9933614,0.003534686,0.0006933068,0.001882452,0.0002167229,0.0003114187],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003240204,0.0003922475,0.005806908,0.0001283146,0.0007865969,0.00005505911,0.0004915451,0.0001572605,0.9656536,0.00001751409,0.0001256187,0.02606134],"study_design_scores_gemma":[0.0006237559,0.000008352585,0.004696492,0.0002282062,0.0009791979,0.00006454512,0.0005982977,0.0003135995,0.9909254,0.000166413,0.0007529441,0.0006428121],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949586,0.002844944,0.0001055321,0.0002087379,0.0001254091,0.0001382212,0.0008248254,0.0002725298,0.0005212149],"genre_scores_gemma":[0.9953577,0.001979967,0.001232493,0.00002179404,0.0001132448,0.0002378003,0.0003007566,0.0001310545,0.0006251683],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02541853,"threshold_uncertainty_score":0.9998621,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01049153544261835,"score_gpt":0.2314846599056505,"score_spread":0.2209931244630322,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}