{"id":"W2112717610","doi":"10.1007/s11144-010-0256-1","title":"Stereoselective hydrogenation of methyl acetoacetate over structurally different chiral ruthenium complexes","year":2010,"lang":"en","type":"article","venue":"Reaction Kinetics Mechanisms and Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"University College of the North","funders":"Akademie Věd České Republiky","keywords":"Ruthenium; Asymmetric hydrogenation; Catalysis; Chemistry; Ammonium; Enantioselective synthesis; Stereoselectivity; Metal; Naphthalene; Noyori asymmetric hydrogenation; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003136472,0.0004622448,0.0004132404,0.0002176764,0.0001867393,0.000262534,0.0006001724,0.0003577568,0.001338571],"category_scores_gemma":[0.0004428578,0.0001826297,0.0001715405,0.000255567,0.0002977503,0.0005038444,0.0003274856,0.0005167018,0.0003525677],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000554104,"about_ca_system_score_gemma":0.0002876181,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001358722,"about_ca_topic_score_gemma":0.001894636,"domain_scores_codex":[0.9997301,0.00005227448,0.00001463645,0.00003226021,0.00004946153,0.000121248],"domain_scores_gemma":[0.999848,0.00003921664,0.00003770151,0.00003421939,0.00002153172,0.00001933217],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001258209,0.0001121381,0.0003640018,0.0002146165,0.00004357214,0.0002549244,0.0001415616,0.001122899,0.981365,0.002400564,0.0006295118,0.01209299],"study_design_scores_gemma":[0.00004095364,0.000195509,0.0003500099,0.0000028908,0.0000125268,0.00007837955,0.00002033006,0.001030477,0.997,0.0001185881,0.001141344,0.000008967925],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9873749,0.001116234,0.003684775,0.0002038582,0.00007292334,0.00003180315,0.0001680719,0.000127607,0.0072198],"genre_scores_gemma":[0.9982767,0.000285793,0.0004682807,0.00002291514,0.000009021717,0.00000612259,0.00005259654,0.00001526782,0.0008632066],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001358722,"threshold_uncertainty_score":0.004477978,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006333802684338988,"score_gpt":0.224877900172538,"score_spread":0.218544097488199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}