{"id":"W2112782625","doi":"10.1039/b501907a","title":"Detoxification pathways of the phytoalexins brassilexin and sinalexin in Leptosphaeria maculans: isolation and synthesis of the elusive intermediate 3-formylindolyl-2-sulfonic acid","year":2005,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Genomics, phytochemicals, and oxidative stress","field":"Biochemistry, Genetics and Molecular Biology","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Leptosphaeria maculans; Chemistry; Crucifer; Metabolite; Blackleg; Sulfonic acid; Bitter taste; Phytoalexin; Phoma; Metabolic pathway; Antifungal; Detoxification (alternative medicine); Stereochemistry; Biochemistry; Organic chemistry; Microbiology; Botany; Metabolism; Biology; Brassica; Gene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001002999,0.000330554,0.0001666031,0.0001614345,0.0001673068,0.0002094044,0.0001167636,0.0002025589,0.0003912678],"category_scores_gemma":[0.00006963463,0.0001156651,0.0002104337,0.00009145762,0.0001395277,0.0001965967,0.0001587833,0.0002536553,0.0002057638],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004339871,"about_ca_system_score_gemma":0.000279113,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001295533,"about_ca_topic_score_gemma":0.001874853,"domain_scores_codex":[0.9999611,0.000006752212,0.000003513299,0.00001202796,0.000008740744,0.00000797536],"domain_scores_gemma":[0.9999343,0.000006322418,0.00002638975,0.00001061263,0.000009186308,0.00001327489],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002243396,0.000003219471,0.0001355327,0.000006628019,8.389479e-7,0.00001115971,0.000007405536,0.0000304079,0.9993425,0.00004112682,0.000002371708,0.000396417],"study_design_scores_gemma":[0.000008823031,0.0001670414,0.009451663,0.000003215568,0.000009507474,0.0001764534,0.00004291106,0.0005936312,0.9884368,0.00009579059,0.001009056,0.000005054416],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972609,0.0005262083,0.001561579,0.00006070745,0.000002933192,0.00001120422,0.000141851,0.000044839,0.0003897051],"genre_scores_gemma":[0.9944639,0.0003073819,0.00281358,0.00003067591,0.000002306869,0.00001968915,0.0005569065,0.00001590791,0.00178975],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001295533,"threshold_uncertainty_score":0.003148794,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004747466639714895,"score_gpt":0.1986648900217037,"score_spread":0.1939174233819888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}