{"id":"W2112782625","doi":"10.1039/b501907a","title":"Detoxification pathways of the phytoalexins brassilexin and sinalexin in Leptosphaeria maculans: isolation and synthesis of the elusive intermediate 3-formylindolyl-2-sulfonic acid","year":2005,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Genomics, phytochemicals, and oxidative stress","field":"Biochemistry, Genetics and Molecular Biology","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Leptosphaeria maculans; Chemistry; Crucifer; Metabolite; Blackleg; Sulfonic acid; Bitter taste; Phytoalexin; Phoma; Metabolic pathway; Antifungal; Detoxification (alternative medicine); Stereochemistry; Biochemistry; Organic chemistry; Microbiology; Botany; Metabolism; Biology; Brassica; Gene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001435837,0.0002020919,0.0002162033,0.00001948338,0.00005910757,0.00001319313,0.0003301041,0.0002040835,0.00002066964],"category_scores_gemma":[0.0002262802,0.0001546181,0.0001001191,0.0001613511,0.0003752111,0.000009156292,0.0002702039,0.0001309729,8.644938e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003914857,"about_ca_system_score_gemma":0.0001058562,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006802552,"about_ca_topic_score_gemma":0.00002862491,"domain_scores_codex":[0.9988666,0.00005945802,0.0003746562,0.0003636596,0.000134569,0.0002010233],"domain_scores_gemma":[0.9990435,0.0000183527,0.0003140357,0.0004990926,0.0000746509,0.00005042135],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004978276,0.00007215599,0.004619722,0.0001031431,0.00003670445,3.558224e-7,0.0001482132,0.000001614176,0.9934325,0.000008095114,0.00001543663,0.001512321],"study_design_scores_gemma":[0.0005308631,0.00002292297,0.01832789,0.0001011187,0.00003596118,0.00001432718,0.0001284188,0.00009672665,0.9803941,0.0000903227,0.00009852774,0.0001588334],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960729,0.001506248,0.001665125,0.0002345106,0.00003462296,0.0002224929,0.00007812602,0.000004583489,0.0001813923],"genre_scores_gemma":[0.9991917,0.0002856801,0.0002639746,0.00007072141,0.00007149113,0.0000161344,0.00003191136,0.00002394967,0.00004442703],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01370817,"threshold_uncertainty_score":0.6305145,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004747466639714895,"score_gpt":0.1986648900217037,"score_spread":0.1939174233819888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}