{"id":"W2113076258","doi":"10.1002/anie.200601229","title":"A σ‐Donor with a Planar Six‐π‐Electron B<sub>2</sub>N<sub>2</sub>C<sub>2</sub> Framework: Anionic N‐Heterocyclic Carbene or Heterocyclic Terphenyl Anion?","year":2006,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Calgary","funders":"","keywords":"Terphenyl; Deprotonation; Carbene; Salt (chemistry); Lithium (medication); Chemistry; Ion; Ligand (biochemistry); Planar; Medicinal chemistry; Combinatorial chemistry; Stereochemistry; Computational chemistry; Organic chemistry; Computer science; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009661909,0.0002519947,0.0002387228,0.00008797278,0.0002366296,0.0003327023,0.0005094424,0.0003640071,0.002780124],"category_scores_gemma":[0.00007476034,0.0001041072,0.00007690709,0.0001504093,0.0001857447,0.000268307,0.0003300646,0.0002394521,0.0007680309],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004665084,"about_ca_system_score_gemma":0.0002842105,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001452492,"about_ca_topic_score_gemma":0.002048671,"domain_scores_codex":[0.9999305,0.000009761397,0.000002482723,0.00001785601,0.00001343194,0.0000258532],"domain_scores_gemma":[0.9999657,0.000003900548,0.000006567825,0.000003656079,0.000004542541,0.000015688],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005903959,0.00006015517,0.0002853351,0.0003544242,0.00001223002,0.000249118,0.00007986368,0.0003188119,0.9803767,0.007149389,0.0009388088,0.009584719],"study_design_scores_gemma":[0.00007782659,0.0005298096,0.0007171609,0.00002429434,0.00001990197,0.0005044796,0.00007782994,0.001289273,0.9745533,0.0003852911,0.02179528,0.0000255998],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9680655,0.001913079,0.008507041,0.000297567,0.00008035713,0.00008310569,0.0004197736,0.000231065,0.02040252],"genre_scores_gemma":[0.9885513,0.0005816069,0.004051579,0.00007966324,0.000008728539,0.00003788533,0.0001568528,0.00001760723,0.006514844],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002780124,"threshold_uncertainty_score":0.009300411,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006996664479881345,"score_gpt":0.2240323129738867,"score_spread":0.2170356484940054,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}