{"id":"W2113102893","doi":"10.1002/chem.201404283","title":"Metalation Kinetics of the Human α‐Metallothionein 1a Fragment Is Dependent on the Fluxional Structure of the apo‐Protein","year":2014,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Trace Elements in Health","field":"Nursing","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Metalation; Chemistry; Cysteine; Crystallography; Kinetics; Stereochemistry; Metal; Stoichiometry; Biochemistry; Enzyme; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001380154,0.0001534181,0.0000973614,0.00009112577,0.00007226254,0.0002106965,0.0001374292,0.0001556424,0.0007069798],"category_scores_gemma":[0.0003093091,0.0001068306,0.00009762609,0.00009532988,0.0001557553,0.0001262856,0.00008432549,0.000276161,0.0002818956],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003090108,"about_ca_system_score_gemma":0.00009244175,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001053103,"about_ca_topic_score_gemma":0.0005892155,"domain_scores_codex":[0.9999163,0.0000122822,0.00000488705,0.00003105079,0.00002098566,0.00001442526],"domain_scores_gemma":[0.9998351,0.00006849199,0.00003606769,0.00001607062,0.00002052713,0.00002360829],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002708506,0.00001628843,0.001021199,0.0000110887,0.000004506496,0.00001951707,0.0000332345,0.00015242,0.9975637,0.00003577825,0.00002069351,0.0008506467],"study_design_scores_gemma":[0.00002331023,0.0002693812,0.02031012,0.000003588991,0.000007746286,0.0001874936,0.00002735214,0.006683648,0.9717898,0.0000614223,0.0006274875,0.000008714368],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9991915,0.0001144126,0.0004738058,0.0000155887,0.000001838064,0.000002709688,0.00007004677,0.00001964444,0.0001105651],"genre_scores_gemma":[0.9983029,0.00008048269,0.0005402,0.000008662653,0.000001649372,0.000004966504,0.0002885142,0.000008263512,0.0007642969],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001053103,"threshold_uncertainty_score":0.002365053,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01634941799285367,"score_gpt":0.2469888485925328,"score_spread":0.2306394305996792,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}