{"id":"W2113454725","doi":"10.1002/anie.200906001","title":"From Discovery to Application: 50 Years of the Vinylcyclopropane–Cyclopentene Rearrangement and Its Impact on the Synthesis of Natural Products","year":2010,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":228,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Cyclopentene; Context (archaeology); Natural (archaeology); Charm (quantum number); Chemistry; History; Organic chemistry; Archaeology; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.003292743,0.0005604658,0.0005013391,0.001016313,0.001322826,0.003608918,0.0006594757,0.001618571,0.002819065],"category_scores_gemma":[0.002538723,0.0003660509,0.0003626286,0.001369492,0.004084447,0.006733225,0.002677496,0.003219483,0.001197016],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002229075,"about_ca_system_score_gemma":0.001525939,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007589774,"about_ca_topic_score_gemma":0.0009214104,"domain_scores_codex":[0.999079,0.0003272774,0.00004649694,0.0001486589,0.0002662475,0.0001322523],"domain_scores_gemma":[0.9992694,0.0003991215,0.00005109203,0.00008386891,0.0001096277,0.00008693599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000525115,0.0001665873,0.0007884124,0.002274845,0.00005011772,0.0009727659,0.005963333,0.0006237183,0.02098423,0.3140939,0.07415219,0.5794048],"study_design_scores_gemma":[0.00001228658,0.0001784751,0.0002794571,0.0004956972,0.00001436836,0.0006872233,0.000617303,0.0001313542,0.01042586,0.03363229,0.9534921,0.0000335092],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.01711172,0.8628715,0.01214329,0.03920679,0.01044122,0.00004052922,0.0001080361,0.0001625843,0.05791433],"genre_scores_gemma":[0.1641923,0.7545605,0.01004889,0.01565381,0.007389408,0.00008579963,0.0001371934,0.0001786035,0.0477536],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.003608918,"threshold_uncertainty_score":0.01741385,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0078394574694516,"score_gpt":0.2460114569447123,"score_spread":0.2381719994752607,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}