{"id":"W2113464168","doi":"10.1039/c2dt31868g","title":"Bulky derivatives of boranes, boronic acids and boronate estersvia reaction with diazomethanes","year":2012,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Boranes; Chemistry; Organic chemistry; Combinatorial chemistry; Hydroboration; Boron; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008217425,0.0002246693,0.0002521598,0.00005693904,0.0001030581,0.0000182899,0.0001016065,0.0001623929,0.0009478922],"category_scores_gemma":[0.000009387767,0.0002045412,0.00005675441,0.000180578,0.0001955494,0.0004189281,0.000006493892,0.0002505812,0.000007426284],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005924454,"about_ca_system_score_gemma":0.00005396245,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008583452,"about_ca_topic_score_gemma":0.0000345963,"domain_scores_codex":[0.9989697,0.00001160961,0.0002487399,0.0002432465,0.0001942464,0.0003324115],"domain_scores_gemma":[0.9992621,0.00008150393,0.0001197086,0.0002968144,0.00005234679,0.0001875344],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008541706,0.0002087871,0.01087214,0.0003347876,0.0001032882,0.000001328179,0.001279079,0.000003492392,0.9828598,0.00004394871,0.00001238451,0.004195552],"study_design_scores_gemma":[0.0007277026,0.00003224003,0.01387385,0.00005270383,0.0001217582,0.00007067195,0.001109109,0.000009327446,0.9795529,0.00001013267,0.00420045,0.0002391644],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958131,0.001231265,0.001002362,0.0001998664,0.0000858136,0.00006502763,0.00008900266,0.0001219519,0.001391622],"genre_scores_gemma":[0.9985503,0.0004544572,0.0003242402,0.000027517,0.00008139673,0.00002305387,0.0000426744,0.00004135483,0.0004550185],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004188065,"threshold_uncertainty_score":0.9999654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01045506932930008,"score_gpt":0.2292838401392484,"score_spread":0.2188287708099483,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}