{"id":"W2113537169","doi":"10.1002/chin.200503193","title":"Total Synthesis of (.+‐.)‐Manzacidin D","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Total synthesis; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000729795,0.0005198704,0.0002945084,0.0003643771,0.0002912512,0.0002641217,0.0003751352,0.0001940651,0.00502004],"category_scores_gemma":[0.00007927974,0.0001153752,0.0001857599,0.0003189316,0.000131281,0.0001460906,0.0002812795,0.0003555252,0.001442248],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003869238,"about_ca_system_score_gemma":0.0007984955,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001515501,"about_ca_topic_score_gemma":0.002213032,"domain_scores_codex":[0.9999499,0.00000590662,0.000003231077,0.00001206783,0.000008856423,0.00002003628],"domain_scores_gemma":[0.9999779,0.000002050904,0.000003239597,0.000003611331,0.000005415503,0.000007833492],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000503593,0.0001891322,0.0003114991,0.0005971297,0.00008145834,0.0007043728,0.00007823372,0.002874549,0.914332,0.009242578,0.00470532,0.06638024],"study_design_scores_gemma":[0.000117058,0.0006739094,0.0009180081,0.00002656517,0.00004662955,0.0003860166,0.00003555057,0.001394809,0.9264679,0.001436197,0.06846674,0.0000306837],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7131853,0.009647813,0.08622592,0.00096689,0.001084885,0.001072014,0.01081789,0.001727048,0.1752723],"genre_scores_gemma":[0.9630737,0.002741363,0.01081736,0.0001896362,0.00002360703,0.0001618067,0.001234242,0.00007456227,0.02168364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00502004,"threshold_uncertainty_score":0.01679373,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006473077462131019,"score_gpt":0.2134087321250456,"score_spread":0.2069356546629146,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}