{"id":"W2113537169","doi":"10.1002/chin.200503193","title":"Total Synthesis of (.+‐.)‐Manzacidin D","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Total synthesis; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005106044,0.0001862121,0.0002571412,0.00002049072,0.00003763162,0.000008318099,0.0002644269,0.0001588805,0.003056541],"category_scores_gemma":[0.0003344915,0.0001876418,0.0001237084,0.0001023659,0.0001364262,0.00010314,0.00009951611,0.0001513023,0.00007981031],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001841932,"about_ca_system_score_gemma":0.0000988702,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009852999,"about_ca_topic_score_gemma":6.29268e-7,"domain_scores_codex":[0.9989262,6.536482e-8,0.0003552891,0.0002036705,0.0002395304,0.0002752854],"domain_scores_gemma":[0.9990832,0.00008334086,0.0001632158,0.0005160461,0.00004727069,0.0001069516],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002166013,0.00008181293,0.00002715479,0.000319696,0.00003581612,0.000007566676,0.0002419454,0.000006405082,0.9281597,0.0003564667,0.0001846196,0.07055717],"study_design_scores_gemma":[0.0003878305,0.000003824367,0.00001138677,0.0001191867,0.00002305611,0.00007405374,0.0004079555,0.000001548896,0.9961669,0.0005666975,0.002035137,0.0002024601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.245818,0.00006753839,0.00001427993,0.00007447664,0.00003505533,0.00002645308,0.00002983711,0.0001112393,0.7538232],"genre_scores_gemma":[0.9923411,0.0000139564,0.0006399652,0.00001401099,0.00009748957,0.00001678921,0.000009676242,0.00003045872,0.006836578],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.7469866,"threshold_uncertainty_score":0.9978548,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006473077462131019,"score_gpt":0.2134087321250456,"score_spread":0.2069356546629146,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}