{"id":"W2113800499","doi":"10.1002/chin.200416068","title":"One‐Pot Synthesis of Homoallylic Ketones from the Addition of Vinyl Grignard Reagent to Carboxylic Esters.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Reactions of Organic Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Reagent; Grignard reagent; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001018804,0.0001673735,0.00031434,0.00004646026,0.00007420107,0.00002121568,0.0004405602,0.0001289577,0.001506736],"category_scores_gemma":[0.0002493963,0.0001313777,0.0001824358,0.0001646606,0.00009934418,0.00009701444,0.0001057392,0.0001134117,0.00003652139],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001543528,"about_ca_system_score_gemma":0.00009711198,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006558536,"about_ca_topic_score_gemma":0.00004656971,"domain_scores_codex":[0.9988484,7.507386e-7,0.000449065,0.0001954539,0.0003173685,0.0001889237],"domain_scores_gemma":[0.9985119,0.0003631716,0.0002408192,0.0007100079,0.00009056195,0.00008353812],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007916329,0.000312081,0.00016436,0.0001606482,0.0003030928,0.000001900718,0.001866415,0.000009235539,0.792305,0.0001230411,0.00300935,0.2016657],"study_design_scores_gemma":[0.0002114737,0.00001621115,0.002206424,0.0003652363,0.000103213,0.000005327279,0.001139994,0.000001595297,0.9884162,0.0001536969,0.007225719,0.0001548968],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8201935,0.0001481324,0.000005960143,0.001071048,0.00009723732,0.0001100506,0.0002113598,0.00005879774,0.1781039],"genre_scores_gemma":[0.9989275,0.00008960631,0.0002084842,0.000052703,0.0001870294,0.00004473561,0.00003904237,0.00002271273,0.0004281486],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2015108,"threshold_uncertainty_score":0.999406,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01458153537221078,"score_gpt":0.2113658467643564,"score_spread":0.1967843113921456,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}