{"id":"W2113817422","doi":"10.1002/ange.200901317","title":"Chemoselektivität und die eigentümlichen Reaktivitäten funktioneller Gruppen","year":2009,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Philosophy; Humanities","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008756863,0.0004647018,0.0003043834,0.0008942138,0.0005071193,0.001301695,0.000412807,0.0006498952,0.008278317],"category_scores_gemma":[0.001035937,0.0002637212,0.0005774642,0.0004762927,0.0009753639,0.00116563,0.0008625811,0.0007234346,0.001419045],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004695585,"about_ca_system_score_gemma":0.0002766264,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004015036,"about_ca_topic_score_gemma":0.0003035528,"domain_scores_codex":[0.9996816,0.00005834227,0.00001669281,0.00008253198,0.00009897946,0.0000618172],"domain_scores_gemma":[0.9994305,0.0002250892,0.0001358424,0.00005389116,0.00009812555,0.00005650644],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0006707542,0.000146819,0.005325862,0.0009962958,0.0001773791,0.0002302169,0.0003098135,0.008310637,0.9026886,0.0297784,0.001484053,0.04988122],"study_design_scores_gemma":[0.00004202693,0.000918608,0.0138599,0.0001183783,0.0001366956,0.0004540372,0.000434619,0.009204324,0.8991811,0.05252589,0.02302605,0.00009841367],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9190064,0.02904013,0.02885471,0.001796675,0.0003903542,0.00006780295,0.0008351774,0.0001567845,0.01985183],"genre_scores_gemma":[0.9825993,0.004944495,0.004244421,0.0002471225,0.00006310357,0.0001149976,0.000363965,0.00003934666,0.007383306],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008278317,"threshold_uncertainty_score":0.02769369,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01247915641521626,"score_gpt":0.2553602178691988,"score_spread":0.2428810614539826,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}