{"id":"W2113826226","doi":"10.1139/v03-077","title":"Intramolecular photosensitization of the pineneocimene rearrangement","year":2003,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institutes of Health","keywords":"Chemistry; Intramolecular force; Moiety; Pinene; Chromophore; Methylene; Photochemistry; Ketone; Cycloaddition; Ring (chemistry); Excited state; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000130747,0.0001229488,0.0001880225,0.00001600882,0.00009573045,0.00001382697,0.0002367643,0.00008798265,0.0007907273],"category_scores_gemma":[0.0001625842,0.0001017919,0.0001452401,0.0001268648,0.0001282923,0.0000309305,0.000005130853,0.000239586,5.711543e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001231204,"about_ca_system_score_gemma":0.0008198826,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001122681,"about_ca_topic_score_gemma":0.0001347634,"domain_scores_codex":[0.9991494,0.00001289667,0.0003285525,0.00009610006,0.0001783735,0.0002346246],"domain_scores_gemma":[0.9991775,0.00001642026,0.0001755777,0.0002267553,0.000194206,0.0002095801],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008240755,0.00001345002,0.0006859261,0.000132495,0.00009499386,0.00002432422,0.0001687459,0.00003184927,0.9980696,0.00002376348,0.0006168119,0.0001297282],"study_design_scores_gemma":[0.0003510311,0.000006462713,0.00005222368,0.0001077532,0.00004290522,0.000137289,0.00021474,0.000001940724,0.9865624,0.000242092,0.01218559,0.00009551761],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9506239,0.0009997719,0.00004937862,0.0001937913,0.00006702663,0.0000263496,0.00001534467,0.000003125876,0.04802127],"genre_scores_gemma":[0.9992735,0.00003150675,0.00004195432,0.00005752568,0.00006413434,0.000001924212,0.000002684686,0.00001188973,0.0005148759],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04864956,"threshold_uncertainty_score":0.8657909,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005294320916485086,"score_gpt":0.1804028613543313,"score_spread":0.1751085404378462,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}