{"id":"W2114150638","doi":"10.1039/b208408b","title":"Alkali-metal ion catalysis and inhibition in nucleophilic displacement reactions at carbon, phosphorus and sulfur centres. IX.For Part VIII see ref. 1. p-Nitrophenyl diphenyl phosphateElectronic supplementary information (ESI) available: kinetic data for the reaction of p-nitrophenyl diphenyl phosphate with various reagents in differing media. See http://www.rsc.org/suppdata/ob/b2/b208408b/","year":2002,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Nucleophile; Phosphorane; Catalysis; Alkali metal; Reactivity (psychology); Inorganic chemistry; Leaving group; Transition metal; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004303326,0.0007051896,0.0006907606,0.0001293131,0.000270069,0.0001059749,0.0004400971,0.0003657219,0.001261926],"category_scores_gemma":[0.0003175159,0.0006503484,0.0001183598,0.0007178187,0.0002184721,0.0005253222,0.0005576227,0.0005278197,0.00001177794],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001142394,"about_ca_system_score_gemma":0.0001038976,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001303812,"about_ca_topic_score_gemma":0.000399302,"domain_scores_codex":[0.9958954,0.00004054805,0.001286667,0.001168881,0.0007000414,0.0009084532],"domain_scores_gemma":[0.9970703,0.0002644305,0.0007643838,0.001485837,0.000155984,0.0002590595],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007854522,0.0003725076,0.0004166884,0.0007539967,0.0002744569,0.00002009448,0.0002876125,0.000005881301,0.9960404,0.000009917409,0.0003032029,0.0007297776],"study_design_scores_gemma":[0.005360863,0.0001052455,0.000231437,0.0003161736,0.000631174,0.0001142609,0.0005661729,0.005969069,0.972093,0.00004152231,0.01390812,0.0006629004],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937956,0.002122874,0.0009667164,0.0003088492,0.0001318104,0.001019082,0.00142707,0.00007349819,0.0001544598],"genre_scores_gemma":[0.9860358,0.003263761,0.0002533923,0.00006864173,0.0001162751,0.0003399423,0.009363828,0.0001213352,0.0004369973],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02394735,"threshold_uncertainty_score":0.9996511,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01056488556863043,"score_gpt":0.2047999875308638,"score_spread":0.1942351019622334,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}