{"id":"W2114181905","doi":"10.1016/j.elecom.2003.12.002","title":"The RC time “constant” at a disk electrode","year":2003,"lang":"en","type":"article","venue":"Electrochemistry Communications","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":false,"ca_institutions":"Trent University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Electrode; Capacitance; Time constant; Dispersion (optics); Constant (computer programming); Current density; Constant current; Materials science; Analytical Chemistry (journal); Mechanics; Current (fluid); Chemistry; Physics; Thermodynamics; Electrical engineering; Optics; Computer science; Physical chemistry; Chromatography; Engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.0002453847,0.0002867347,0.0002449096,0.00002062969,0.002025352,0.0001124587,0.001813089,0.0001565347,0.0008540323],"category_scores_gemma":[0.0002793594,0.0002341856,0.0002468475,0.0005185371,0.0004054913,0.0000549469,0.0002505491,0.0006661784,0.0004144705],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003551687,"about_ca_system_score_gemma":0.0001755799,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004652594,"about_ca_topic_score_gemma":0.00003977536,"domain_scores_codex":[0.9980503,0.00006178189,0.0004791672,0.0004173838,0.0002762869,0.0007150759],"domain_scores_gemma":[0.9954425,0.0006614302,0.0002204206,0.003364808,0.0001272454,0.0001835698],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009196428,0.0001281425,0.00009660595,0.000007552416,0.0001110269,2.532424e-7,0.00002131611,8.687034e-7,0.9756052,0.01841901,0.00499176,0.0006090883],"study_design_scores_gemma":[0.0001507527,0.00000569343,0.000002858669,0.000007935411,0.00006626321,0.00003531728,0.00002552456,0.0004407638,0.6605085,0.00527163,0.3332662,0.000218548],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1467809,0.01213219,0.000442886,0.007416175,0.00001097419,0.0002008425,0.00004125821,0.0004868898,0.8324879],"genre_scores_gemma":[0.9567003,0.002162528,0.0008421708,0.0001594774,0.00005564414,0.0003630637,0.000320541,0.0000439415,0.03935235],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8099194,"threshold_uncertainty_score":0.9992739,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006337386165908075,"score_gpt":0.2286034096488216,"score_spread":0.2222660234829135,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}