{"id":"W2114539152","doi":"10.1139/v00-190","title":"Rh<sub>2</sub>Cl<sub>2</sub>(CO)<sub>4</sub> adsorbed and tethered on gold powder: IR spectroscopic characterization and olefin hydrogenation activity","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Catalysis; Rhodium; Olefin fiber; Adsorption; Medicinal chemistry; Fourier transform infrared spectroscopy; Inorganic chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009306425,0.0003626978,0.0003344077,0.0002634171,0.0001325272,0.0003253208,0.0003648404,0.0004036037,0.001596746],"category_scores_gemma":[0.0002556479,0.0002529219,0.0001840466,0.0001523312,0.0002545451,0.0002315257,0.000238803,0.0002946055,0.0004774755],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003963107,"about_ca_system_score_gemma":0.0001183359,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001240764,"about_ca_topic_score_gemma":0.002354183,"domain_scores_codex":[0.9998237,0.00001112837,0.00001056698,0.00003130497,0.00007988099,0.00004333736],"domain_scores_gemma":[0.9999111,0.00001617318,0.00001888236,0.00001676096,0.00002339989,0.00001373919],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004727801,0.000006153752,0.0002131027,0.00002499084,0.000004799746,0.00002714554,0.000007156404,0.00006665927,0.9990571,0.00002033332,0.00001919164,0.0005060093],"study_design_scores_gemma":[0.000002881525,0.00003281239,0.00135425,0.000001072435,0.00000491512,0.00003342568,0.000007871295,0.0004622596,0.9978526,0.000006054326,0.0002402059,0.000001769404],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956248,0.0002365205,0.002200357,0.0000471088,0.00001288253,0.0000214758,0.0001752713,0.0001151968,0.001566279],"genre_scores_gemma":[0.9947983,0.0001243922,0.00239946,0.00003360145,0.000004107937,0.00002129544,0.0003089988,0.00003666945,0.002273117],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001596746,"threshold_uncertainty_score":0.005341649,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004524494159965221,"score_gpt":0.1783732959510488,"score_spread":0.1738488017910836,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}