{"id":"W2114772076","doi":"10.1002/adfm.200902300","title":"Highly Emissive and Electrochemically Stable Thienylene Vinylene Oligomers and Copolymers: An Unusual Effect of Alkylsulfanyl Substituents","year":2010,"lang":"en","type":"article","venue":"Advanced Functional Materials","topic":"Organic Electronics and Photovoltaics","field":"Engineering","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique; McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Materials science; Cyclic voltammetry; Photoluminescence; Thermal stability; Amorphous solid; Conjugated system; Polymer; Quantum yield; Condensation polymer; Electrochemistry; HOMO/LUMO; Organic semiconductor; Polymer chemistry; Chemical engineering; Physical chemistry; Organic chemistry; Optoelectronics; Fluorescence; Molecule; Electrode; Chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001714657,0.0002170647,0.0003098901,0.00006666366,0.00005721486,0.00003260596,0.00007514574,0.0001313015,0.0001353952],"category_scores_gemma":[0.0000467501,0.0002038992,0.00002067695,0.0001112192,0.00008082581,0.0002385086,0.00002901614,0.0001613465,0.000002880425],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002690237,"about_ca_system_score_gemma":0.00002859376,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001557284,"about_ca_topic_score_gemma":0.00000951258,"domain_scores_codex":[0.9990273,0.00002346457,0.0002468853,0.000246067,0.0001552737,0.0003010708],"domain_scores_gemma":[0.9994809,0.0001053749,0.00006457249,0.0001635717,0.00005222084,0.0001333364],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000211158,0.0000149519,0.0001474555,0.0001052965,0.00005239422,0.000001372207,0.00002712186,0.00006905581,0.9980025,0.0007238342,0.00001846851,0.0006263962],"study_design_scores_gemma":[0.0008264478,0.0003488552,0.0007119218,0.00001803984,0.00003718773,0.00002793562,0.00000777912,0.00005614276,0.9969487,0.000390536,0.0004248465,0.0002016103],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982338,0.0005640267,0.00009893445,0.00001247004,0.0006003162,0.00017531,0.0000731285,0.00008906358,0.0001529457],"genre_scores_gemma":[0.9989968,0.0003769532,0.0002985176,0.0000229249,0.0001142661,0.00002300303,0.00007960073,0.00004171419,0.00004621236],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001053798,"threshold_uncertainty_score":0.8314767,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002413591866011089,"score_gpt":0.1916773376947219,"score_spread":0.1892637458287108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}