{"id":"W2114912727","doi":"10.1002/chem.201404705","title":"[(IPent)PdCl<sub>2</sub>(morpholine)]: A Readily Activated Precatalyst for Room‐Temperature, Additive‐Free Carbon–Sulfur Coupling","year":2014,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; York University","funders":"Natural Sciences and Engineering Research Council of Canada; Eli Lilly and Company","keywords":"Morpholine; Chemistry; Sulfur; Aryl; Alkyl; Halide; Ligand (biochemistry); Catalysis; Carbon fibers; Medicinal chemistry; Activated carbon; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00173059,0.0008598971,0.0007762881,0.000122908,0.000544261,0.0004464686,0.001781311,0.0003177306,0.0004021827],"category_scores_gemma":[0.002771424,0.0008627229,0.0005650558,0.0002993912,0.0001968919,0.0002645368,0.0003101102,0.001777851,0.00003462628],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004046709,"about_ca_system_score_gemma":0.0002466047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000312285,"about_ca_topic_score_gemma":0.000001020477,"domain_scores_codex":[0.9958858,0.0001484986,0.001192836,0.001027171,0.0006803933,0.001065335],"domain_scores_gemma":[0.9955482,0.0005500691,0.0009998196,0.001586454,0.0006113185,0.0007041646],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003452322,0.000207743,0.0000654636,0.0002950965,0.000218956,0.0001926357,0.00009567401,0.00003741761,0.9838538,0.000002338341,0.009894811,0.004790831],"study_design_scores_gemma":[0.002306055,0.00006487159,0.00005470922,0.0008723455,0.0001936415,0.0008734569,0.0001563651,0.001159163,0.9776977,0.00006767976,0.01561725,0.0009367117],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9752568,0.0002045382,0.0003539038,0.0001675914,0.0001626196,0.000235324,0.0003350972,0.0006687166,0.02261543],"genre_scores_gemma":[0.9935552,0.0001094775,0.001385309,0.0001451875,0.003030981,0.00008873214,0.0004089409,0.0003882053,0.0008879276],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0217275,"threshold_uncertainty_score":0.9993824,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01164233066021,"score_gpt":0.2148395833110431,"score_spread":0.203197252650833,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}