{"id":"W2115086312","doi":"10.1039/c0dt00400f","title":"Rapid assembly of explicit, functional silicones","year":2010,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Hydrosilylation; Silylation; Chemistry; Alkyl; Silicone; Yield (engineering); Catalysis; Functional group; Halide; Organic chemistry; Polymer; Thiol; Polymer chemistry; Combinatorial chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002314056,0.0004629931,0.0002040852,0.0002306509,0.0001308124,0.0002505465,0.00021846,0.0002909853,0.001883336],"category_scores_gemma":[0.0002826826,0.0002804959,0.0002417437,0.0001693479,0.0001885087,0.0004276323,0.0004265501,0.0006092574,0.001055977],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001935399,"about_ca_system_score_gemma":0.0001302378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001049105,"about_ca_topic_score_gemma":0.0003150174,"domain_scores_codex":[0.9998308,0.0000176363,0.00001704789,0.0000335949,0.00005968428,0.00004111801],"domain_scores_gemma":[0.9998935,0.00002333937,0.00002381637,0.0000141093,0.00001547941,0.00002969059],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000286006,0.00001030402,0.00003633508,0.00003822372,0.000003899072,0.00005022861,0.00002356735,0.000217385,0.9967391,0.0003169316,0.00008969969,0.00244563],"study_design_scores_gemma":[0.000008576902,0.0001063991,0.0003286648,0.000004235561,0.000006036728,0.00009262603,0.000008373186,0.001129151,0.993147,0.00007276474,0.005089088,0.00000712642],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9443467,0.002416444,0.03893542,0.0001466785,0.0002046776,0.0001295122,0.0005834004,0.0009561758,0.01228097],"genre_scores_gemma":[0.9643162,0.001334629,0.02453246,0.0001077649,0.00003505013,0.00007004958,0.0007226396,0.0001395784,0.008741526],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001883336,"threshold_uncertainty_score":0.00630033,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01473129046921877,"score_gpt":0.2296919270783801,"score_spread":0.2149606366091613,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}