{"id":"W2115293107","doi":"10.1002/anie.201506751","title":"Formal Direct Cross‐Coupling of Phenols with Amines","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":198,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Amination; Phenols; Aryl; Halide; Chemistry; Coupling reaction; Palladium; Catalysis; Organic chemistry; Coupling (piping); Primary (astronomy); Combinatorial chemistry; Materials science; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004015281,0.0008164922,0.0003095717,0.0002586956,0.0002319209,0.0002155041,0.0004970576,0.0003396,0.004492618],"category_scores_gemma":[0.0003649789,0.0002670283,0.0003699788,0.0002138021,0.0003072599,0.0003942222,0.0008386141,0.001060142,0.001828091],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003939799,"about_ca_system_score_gemma":0.0004015533,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006943514,"about_ca_topic_score_gemma":0.001246055,"domain_scores_codex":[0.999619,0.0000443261,0.00003082978,0.00008124115,0.00008578566,0.0001387525],"domain_scores_gemma":[0.9998418,0.00002666782,0.00003323659,0.00002903125,0.00003830517,0.00003100799],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009903029,0.00006429739,0.0001095413,0.0006796915,0.00005385334,0.0005808423,0.0001872541,0.0005473107,0.9804997,0.003386845,0.000922406,0.01286924],"study_design_scores_gemma":[0.00002299509,0.0003231142,0.0003638259,0.00001955891,0.00002534328,0.0004290103,0.0000168977,0.0004448027,0.981455,0.0002915772,0.01659083,0.00001693955],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8292698,0.01255431,0.1043381,0.0006823355,0.0009055006,0.0003949883,0.001265659,0.001372263,0.04921709],"genre_scores_gemma":[0.9663579,0.00618409,0.01594794,0.0002082556,0.00007036976,0.0001322806,0.0007064831,0.000122556,0.01027008],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004492618,"threshold_uncertainty_score":0.01502925,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02498181290837905,"score_gpt":0.2919821255903022,"score_spread":0.2670003126819232,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}