{"id":"W2115293107","doi":"10.1002/anie.201506751","title":"Formal Direct Cross‐Coupling of Phenols with Amines","year":2015,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":198,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Amination; Phenols; Aryl; Halide; Chemistry; Coupling reaction; Palladium; Catalysis; Organic chemistry; Coupling (piping); Primary (astronomy); Combinatorial chemistry; Materials science; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001256356,0.0001474031,0.0001579796,0.00006861796,0.00005913283,0.00007902583,0.0002050338,0.00009335131,0.0003956119],"category_scores_gemma":[0.0002337613,0.0001370735,0.00007470178,0.000102909,0.0001476087,0.00057698,0.00006206566,0.0001325946,0.00002236825],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002035776,"about_ca_system_score_gemma":0.00007212897,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001262604,"about_ca_topic_score_gemma":0.00002551346,"domain_scores_codex":[0.9987991,1.530208e-7,0.0002839829,0.0002326103,0.0004986835,0.0001854699],"domain_scores_gemma":[0.9987825,0.00008676347,0.0002185614,0.000210983,0.0006108864,0.00009026693],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002792046,0.0001924497,0.009305092,0.00006976954,0.0001523462,0.00001115696,0.0003614251,0.001600532,0.984777,0.0001774185,0.002829131,0.0002444864],"study_design_scores_gemma":[0.001017315,0.00002110736,0.0005146598,0.0001082148,0.00003182844,0.00004292934,0.0002325275,0.0009643867,0.9933719,0.0001804139,0.003358189,0.0001565171],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9719999,0.00004946698,0.0006515961,0.0001272088,0.0005968291,0.00004413967,0.0002071196,0.0001102177,0.02621349],"genre_scores_gemma":[0.9955819,0.00001040449,0.00009449528,0.00001886382,0.001463968,0.00003411531,0.0008997357,0.00002542364,0.001871078],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02434242,"threshold_uncertainty_score":0.5589696,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02498181290837905,"score_gpt":0.2919821255903022,"score_spread":0.2670003126819232,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}