{"id":"W2115786060","doi":"10.1002/anie.200702908","title":"Metal‐Free Catalytic Hydrogenation","year":2007,"lang":"de","type":"article","venue":"Angewandte Chemie International Edition","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":622,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Phosphonium; Steric effects; Catalysis; Chemistry; Metal; Boron; Catalytic hydrogenation; Combinatorial chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.001082089,0.0005203518,0.0004156672,0.0006965814,0.0002359843,0.0001930184,0.001096956,0.0005609512,0.005528728],"category_scores_gemma":[0.001238969,0.0005925948,0.0005259983,0.0009500242,0.0001792241,0.0007474466,0.0002910156,0.0005485405,0.00180397],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0012086,"about_ca_system_score_gemma":0.0001468379,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001167749,"about_ca_topic_score_gemma":0.00004408727,"domain_scores_codex":[0.9955533,0.00002227469,0.001101838,0.0008437879,0.001843583,0.0006351768],"domain_scores_gemma":[0.9969856,0.0003122779,0.0007090098,0.0008178359,0.0008104579,0.000364882],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006955682,0.002831594,0.001725173,0.0005395601,0.008126803,0.0006064613,0.002229344,0.0001313628,0.6266426,0.007581595,0.2932775,0.05561235],"study_design_scores_gemma":[0.00136249,0.0000208013,0.0001393962,0.00007620335,0.0004719855,0.00003492536,0.0003112484,0.000456509,0.7975499,0.001025921,0.1980612,0.0004894144],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.07284818,0.01290427,0.0770668,0.01151711,0.02738003,0.0009009156,0.004061469,0.001151883,0.7921693],"genre_scores_gemma":[0.964955,0.0006901427,0.0002522545,0.0006970999,0.01026663,0.00003697496,0.01215828,0.00008761102,0.01085606],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8921068,"threshold_uncertainty_score":0.9996526,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01334219460199833,"score_gpt":0.2576056701772862,"score_spread":0.2442634755752879,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}