{"id":"W2115793706","doi":"10.1139/v06-025","title":"Facile synthesis of α-<scp>D</scp>-Ara<i>f-</i>(1→5)-<scp>D</scp>-Gal<i>f</i>, the linker unit of the arabinan to the galactan in <i>Mycobacterium tuberculosis</i>","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Agencia Nacional de Promoción Científica y Tecnológica","keywords":"Chemistry; Furanose; Stereochemistry; Arabinogalactan; Arabinose; Glycosylation; Galactan; Synthon; Linker; Polysaccharide; Xylose; Biochemistry; Organic chemistry; Fermentation; Ring (chemistry)","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008945353,0.0005646407,0.0008611791,0.0001103736,0.0003047676,0.000131973,0.002391594,0.0004755369,0.0002984549],"category_scores_gemma":[0.003119593,0.0003705327,0.0007262189,0.000917292,0.0006456642,0.0001541824,0.0001357063,0.001234325,0.000009544193],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003663032,"about_ca_system_score_gemma":0.001592782,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00282255,"about_ca_topic_score_gemma":0.00367817,"domain_scores_codex":[0.9962545,0.000124376,0.001528969,0.0004129339,0.0007368515,0.0009423586],"domain_scores_gemma":[0.9943328,0.00195176,0.001124849,0.001481001,0.0004999769,0.0006095573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001456182,0.0001039838,0.01540769,0.0004721738,0.0001766115,0.00007227308,0.001096952,0.0005049296,0.9622824,0.00001720757,0.01961168,0.0002394943],"study_design_scores_gemma":[0.000326272,0.00001160444,0.003352862,0.0006391109,0.0001909529,0.0002572591,0.003239671,0.00001722222,0.9045966,0.0001449844,0.08709694,0.0001265774],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9376706,0.0009332066,0.000002601755,0.001354391,0.0002086228,0.0001377258,0.0004930093,0.00001278492,0.05918706],"genre_scores_gemma":[0.9938396,0.00006678573,0.0000270912,0.00021013,0.0006183877,0.00002948008,0.00001451218,0.00007207882,0.005121969],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06748526,"threshold_uncertainty_score":0.9998747,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007429815624582137,"score_gpt":0.1830426604498107,"score_spread":0.1756128448252285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}