{"id":"W2116189153","doi":"10.1039/c3cc45284k","title":"Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect","year":2013,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Zeolite; Halide; Cluster (spacecraft); Polymer; Chemistry; Luminescence; Crystallography; Coordination polymer; Polymer chemistry; Void (composites); Inorganic chemistry; Materials science; Organic chemistry; Catalysis; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007795224,0.000190211,0.0001591911,0.0001049845,0.0001860242,0.0003313323,0.0003021634,0.0002581912,0.0006768871],"category_scores_gemma":[0.0001335826,0.0001792035,0.0001214001,0.00006723571,0.0002482355,0.0002142797,0.00036789,0.0002234406,0.0002102619],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000325321,"about_ca_system_score_gemma":0.0001722022,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005252954,"about_ca_topic_score_gemma":0.0008145184,"domain_scores_codex":[0.999907,0.00001213082,0.000004094249,0.00003108558,0.00002052338,0.00002516506],"domain_scores_gemma":[0.9999307,0.000008541981,0.00001566425,0.00001210002,0.000005187044,0.00002774793],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008212956,0.00001412653,0.0002221613,0.00004633206,0.000008632542,0.0001439634,0.00004401973,0.0002196885,0.9969261,0.0006675199,0.0001071344,0.001518126],"study_design_scores_gemma":[0.00002007102,0.0001477489,0.001345136,0.000002210048,0.000006752031,0.000268471,0.00002183131,0.0009730328,0.9952555,0.00008006243,0.001870672,0.000008455475],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940779,0.0002223251,0.002726319,0.00006256393,0.0000115818,0.00002039566,0.00008545068,0.0001900841,0.002603376],"genre_scores_gemma":[0.9970714,0.0000589281,0.001938358,0.00002106692,0.000002566851,0.00001411983,0.00008166685,0.00002347636,0.0007883553],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006768871,"threshold_uncertainty_score":0.002360404,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01682843411994768,"score_gpt":0.2695512108155936,"score_spread":0.2527227766956459,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}