{"id":"W2116667212","doi":"10.1039/c4sc03775h","title":"Two-photon sensitive protecting groups operating via intramolecular electron transfer: uncaging of GABA and tryptophan","year":2015,"lang":"en","type":"article","venue":"Chemical Science","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"Engineering and Physical Sciences Research Council; European Commission","keywords":"Intramolecular force; Tryptophan; Photochemistry; Electron transfer; Chemistry; Photoinduced electron transfer; Excitation; Sensitivity (control systems); Two-photon excitation microscopy; Modular design; Combinatorial chemistry; Organic chemistry; Computer science; Amino acid; Physics; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001490784,0.0004448894,0.0001629462,0.0001329932,0.00009707717,0.0001948005,0.0002726403,0.0003838491,0.000700652],"category_scores_gemma":[0.0001651949,0.0001642061,0.0002437185,0.0001030396,0.0002300847,0.0003333353,0.0003037225,0.0004161464,0.0002699505],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001468127,"about_ca_system_score_gemma":0.00009554593,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001411021,"about_ca_topic_score_gemma":0.0001779866,"domain_scores_codex":[0.9999175,0.00001390038,0.000005374459,0.00002295049,0.00001830237,0.00002195827],"domain_scores_gemma":[0.9998546,0.00003537724,0.00006114622,0.00002412086,0.00001091072,0.00001374783],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003512837,0.000009714282,0.00004227409,0.00004044592,0.000003026864,0.00003343718,0.0000134287,0.0001123398,0.9982169,0.0001377145,0.000009851284,0.001345719],"study_design_scores_gemma":[0.000005093812,0.00009024135,0.0001841403,0.000001281696,0.000003322076,0.00005267312,0.000003056093,0.0002219513,0.9989028,0.00001557503,0.000517318,0.000002565742],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9794017,0.0008770674,0.01823184,0.00004899191,0.00001747227,0.00003876337,0.00005641032,0.0001055273,0.00122218],"genre_scores_gemma":[0.9858918,0.0006009964,0.01183336,0.00003328242,0.000006970723,0.00004224179,0.0000672571,0.0000246962,0.001499489],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000700652,"threshold_uncertainty_score":0.002343893,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01069887551196143,"score_gpt":0.2472991641505854,"score_spread":0.2366002886386239,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}