{"id":"W2116929930","doi":"10.1002/anie.200602353","title":"A Melt Approach to the Synthesis of catenaâPhosphorus Dications To Access Derivatives of [P6Ph4R4]2+","year":2006,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Dalhousie University","funders":"","keywords":"Cyclohexane; Chemistry; Yield (engineering); Phosphorus; Computational chemistry; Organic chemistry; Materials science; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006465513,0.0003003814,0.0001893511,0.000134687,0.0002120485,0.0002505933,0.0003000858,0.0002312598,0.003037794],"category_scores_gemma":[0.0001330492,0.0001828514,0.0001731161,0.0001388088,0.0002022792,0.0002697141,0.0003653665,0.0006237327,0.0006524763],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001510451,"about_ca_system_score_gemma":0.0001630194,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002230788,"about_ca_topic_score_gemma":0.0003026711,"domain_scores_codex":[0.9999279,0.000009339333,0.000008956778,0.00002170793,0.00001853731,0.00001355213],"domain_scores_gemma":[0.9999492,0.000007409022,0.00001664601,0.00001098875,0.000007369221,0.000008294894],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001219322,0.00002433779,0.00007150653,0.0001318992,0.00001007494,0.0001557767,0.00008482158,0.0001645844,0.9893393,0.002208926,0.0003311282,0.007355801],"study_design_scores_gemma":[0.00002177525,0.0002338394,0.0001918179,0.00000544182,0.000007661005,0.0002886798,0.00002387849,0.0003212346,0.992341,0.0002108817,0.00634743,0.000006381687],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9033667,0.002353043,0.05934172,0.0005211665,0.0002273315,0.0003671931,0.0007402905,0.0008340138,0.03224852],"genre_scores_gemma":[0.9702016,0.00137676,0.0222953,0.0001030766,0.00002792438,0.0001464355,0.0002371533,0.00009300734,0.005518923],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003037794,"threshold_uncertainty_score":0.01016241,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01446123334214805,"score_gpt":0.2338232051196436,"score_spread":0.2193619717774956,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}