{"id":"W2117282934","doi":"10.1002/0471264180.os078.26","title":"Methyl Carbamate Formation Via Modified <scp>H</scp> ofmann Rearrangement Reactions: Methyl N‐(p‐Methoxyphenyl)Carbamate","year":2003,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Quinazolinone synthesis and applications","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Carbamate; Chemistry; Benzamide; Ethyl carbamate; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0007755519,0.001016558,0.001170534,0.000468792,0.000322008,0.0001929538,0.0008375613,0.00100723,0.01467511],"category_scores_gemma":[0.001556004,0.0009842265,0.0004149521,0.0005529047,0.0001648069,0.0002064603,0.0001690944,0.0006350682,0.001810862],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003497077,"about_ca_system_score_gemma":0.0001330958,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004596538,"about_ca_topic_score_gemma":0.0001129976,"domain_scores_codex":[0.9958026,0.0002646825,0.001104863,0.001125888,0.0007889622,0.000913051],"domain_scores_gemma":[0.9949737,0.001254377,0.001259713,0.00206667,0.0001512458,0.0002943052],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000009025346,0.0004545394,0.00001098897,0.001456731,0.0009970197,0.00001448641,0.0005484315,0.00001104877,0.7128006,0.001767168,0.2674651,0.01446478],"study_design_scores_gemma":[0.000226718,0.00001263902,0.000004429122,0.0006423501,0.0004898341,0.0000362,0.0007318409,0.0001206442,0.2710136,0.0006972653,0.725626,0.0003984853],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.001190739,0.003954957,0.008799322,0.0002207888,0.0005487983,0.0007506575,0.0004556675,0.001316828,0.9827622],"genre_scores_gemma":[0.03241369,0.00524117,0.007750973,0.0001934047,0.001163711,0.001235249,0.0003796075,0.002106107,0.9495161],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.4581608,"threshold_uncertainty_score":0.9992608,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02469239583164337,"score_gpt":0.2531208629074794,"score_spread":0.2284284670758361,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}