{"id":"W2117592814","doi":"10.5194/amt-9-1473-2016","title":"Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds","year":2016,"lang":"en","type":"article","venue":"Atmospheric measurement techniques","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Biological and Environmental Research; Woods Hole Oceanographic Institution; Directorate for Geosciences; University of Toronto; Office of Science; National Aeronautics and Space Administration; U.S. Department of Energy; National Science Foundation","keywords":"Chemistry; Chemical ionization; Atmospheric-pressure chemical ionization; Benzene; Mass spectrometry; Isoprene; Analytical Chemistry (journal); Ionization; Dimethyl sulfide; Ion; Organic chemistry; Sulfur; Chromatography","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006767504,0.000136371,0.0001736828,0.000001012814,0.0001788728,0.00002622339,0.0001634453,0.00006854696,0.0002993096],"category_scores_gemma":[0.0003072974,0.00007919032,0.00005834263,0.0002040555,0.00009494042,0.0001241674,0.00001763821,0.00005694784,0.000002134158],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002067409,"about_ca_system_score_gemma":0.00006048875,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001193684,"about_ca_topic_score_gemma":0.00004069509,"domain_scores_codex":[0.9989603,0.0000408618,0.0003042149,0.0002232889,0.0002813234,0.0001900136],"domain_scores_gemma":[0.9989733,0.0003716374,0.0001648921,0.000210861,0.0002259808,0.00005329935],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007256537,0.00003105733,0.126837,0.0001316788,0.0001066588,3.072437e-7,0.0001327976,0.00001993705,0.6896542,0.00007452811,0.002985829,0.1799534],"study_design_scores_gemma":[0.0007906375,0.0002213829,0.04742094,0.0004190162,0.000209402,0.00001880205,0.0001263298,0.008217908,0.9287314,0.001418594,0.01188253,0.0005430147],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5182197,0.003198743,0.4727345,0.002196427,0.0001486718,0.001468665,0.00003792423,0.0004277452,0.001567592],"genre_scores_gemma":[0.9547682,0.0001568116,0.04470718,0.00009764234,0.0001194841,0.00001771213,0.00001297656,0.000007476585,0.0001125361],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4365484,"threshold_uncertainty_score":0.327723,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01854423843388215,"score_gpt":0.218048546412821,"score_spread":0.1995043079789389,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}