{"id":"W2117660548","doi":"10.1139/v06-002","title":"Reaction of H<sub>2</sub>S with MoRu(CO)<sub>6</sub>(dppm)<sub>2</sub> to give H<sub>2</sub> and a bridged-sulfide product via hydrido-sulfhydryl intermediates (dppm = Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Toluene; Molybdenum; Yield (engineering); Sulfide; Sulfur; Hydrogen sulfide; Ruthenium; Medicinal chemistry; Oxidative addition; Methane; Carbyne; Stereochemistry; Catalysis; Inorganic chemistry; Organic chemistry; Carbene","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.003219798,0.005053138,0.005672268,0.003786835,0.001906854,0.001369233,0.003917131,0.003078721,0.0001233565],"category_scores_gemma":[0.002857335,0.005559143,0.002844524,0.006668892,0.002659876,0.002952207,0.0007907365,0.006363794,0.000556605],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.005195045,"about_ca_system_score_gemma":0.006413108,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001165614,"about_ca_topic_score_gemma":0.008323203,"domain_scores_codex":[0.9750998,0.000680786,0.007498457,0.005367252,0.005244858,0.006108872],"domain_scores_gemma":[0.9756415,0.001180785,0.007121425,0.004489058,0.003790211,0.007776987],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00133467,0.001107411,0.003428862,0.00176583,0.002515909,0.002217519,0.001318203,0.0009713559,0.9287984,0.00001622734,0.01856772,0.03795793],"study_design_scores_gemma":[0.007347219,0.0006134899,0.002574062,0.002275689,0.002444021,0.00511542,0.001548557,0.000533888,0.9693702,0.0003519547,0.002303755,0.005521673],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9846775,0.004235298,0.0007650494,0.001807261,0.001455651,0.001918186,0.001949891,0.0005844035,0.002606753],"genre_scores_gemma":[0.9863676,0.003086969,0.0001610895,0.001101454,0.005235808,0.0004359728,0.002185671,0.001294093,0.0001313458],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04057191,"threshold_uncertainty_score":0.9996675,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004853606469776087,"score_gpt":0.1901157494960767,"score_spread":0.1852621430263006,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}