{"id":"W2117660548","doi":"10.1139/v06-002","title":"Reaction of H<sub>2</sub>S with MoRu(CO)<sub>6</sub>(dppm)<sub>2</sub> to give H<sub>2</sub> and a bridged-sulfide product via hydrido-sulfhydryl intermediates (dppm = Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Toluene; Molybdenum; Yield (engineering); Sulfide; Sulfur; Hydrogen sulfide; Ruthenium; Medicinal chemistry; Oxidative addition; Methane; Carbyne; Stereochemistry; Catalysis; Inorganic chemistry; Organic chemistry; Carbene","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005946646,0.0002306954,0.0001527171,0.00008114735,0.00009899421,0.0001641864,0.0001425111,0.0001815107,0.001694942],"category_scores_gemma":[0.0001041441,0.0001280305,0.0001237318,0.00007474153,0.0001389837,0.0001533321,0.0002368149,0.0002689784,0.0003220899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002032788,"about_ca_system_score_gemma":0.0001504575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006148765,"about_ca_topic_score_gemma":0.00216149,"domain_scores_codex":[0.9999512,0.000004920077,0.000001940838,0.000009365007,0.00001427244,0.00001829174],"domain_scores_gemma":[0.9999691,0.000004895182,0.000009380818,0.000003799233,0.000005173539,0.000007589388],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001318498,0.00001532554,0.0005154264,0.00007718201,0.00002180917,0.000121227,0.00004656072,0.0002084872,0.9957396,0.000323344,0.0001601878,0.002639003],"study_design_scores_gemma":[0.000004072931,0.0001099212,0.001545461,0.000002913331,0.000007001946,0.000121822,0.00002653249,0.0005473839,0.9949682,0.00004873036,0.002613984,0.000003949721],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992136,0.0005039885,0.003818076,0.00007219408,0.00005252777,0.00003841932,0.0001263844,0.0000915024,0.003160975],"genre_scores_gemma":[0.9951905,0.0002084713,0.001814206,0.00002409799,0.000006956363,0.0000158173,0.0001182564,0.00001534089,0.002606289],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001694942,"threshold_uncertainty_score":0.00567019,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004853606469776087,"score_gpt":0.1901157494960767,"score_spread":0.1852621430263006,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}