{"id":"W2118660903","doi":"10.1021/bi050902i","title":"Roles of the Equatorial Tyrosyl Iron Ligand of Protocatechuate 3,4-Dioxygenase in Catalysis<sup>,</sup>","year":2005,"lang":"en","type":"article","venue":"Biochemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"National Institute of General Medical Sciences","keywords":"Dioxygenase; Chemistry; Ligand (biochemistry); Catalysis; Stereochemistry; Biochemistry; Enzyme; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000183221,0.0002835717,0.0001470267,0.00005832819,0.0001759872,0.0004609872,0.0002640016,0.0002848187,0.0007017539],"category_scores_gemma":[0.0001885839,0.0001518386,0.0001110678,0.00005406762,0.0003215849,0.0002585016,0.0001898224,0.0002410891,0.0004427808],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004378467,"about_ca_system_score_gemma":0.0002137732,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009431114,"about_ca_topic_score_gemma":0.0007445248,"domain_scores_codex":[0.9999169,0.00002008737,0.00000851119,0.00001526995,0.00002029626,0.00001894968],"domain_scores_gemma":[0.9998908,0.00002467239,0.0000319819,0.000009878019,0.00001475219,0.00002786804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006024746,0.00003337937,0.003383493,0.0000824099,0.000007951839,0.000281398,0.0000463019,0.00067058,0.9890832,0.000944429,0.00009783432,0.004766428],"study_design_scores_gemma":[0.00002067752,0.0002126571,0.006242578,0.000006181246,0.00001657832,0.0004837427,0.00009771137,0.006637672,0.9840602,0.0003003288,0.001912832,0.000008855475],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961045,0.0005736127,0.002237924,0.0001265293,0.00001313802,0.000005097187,0.00005263206,0.00004035606,0.000846178],"genre_scores_gemma":[0.9973595,0.0001955075,0.001621566,0.00004210534,0.00000660824,0.000004152776,0.000106294,0.00001091432,0.0006533401],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009431114,"threshold_uncertainty_score":0.003176749,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01003510908322507,"score_gpt":0.2315320398736085,"score_spread":0.2214969307903834,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}