{"id":"W2119076668","doi":"10.1139/cjc-2013-0068","title":"Halogenated poly(isobutylene-co-isoprene): influence of halogen leaving-group and polymer microstructure on chemical reactivity","year":2013,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Polymer Nanocomposites and Properties","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Johns Hopkins University","keywords":"Isobutylene; Dehydrohalogenation; Reactivity (psychology); Chemistry; Nucleophile; Nucleophilic substitution; Isoprene; Polymer chemistry; Vulcanization; Microstructure; Butyl rubber; Natural rubber; Organic chemistry; Sulfur; Substituent; Polymer; Copolymer; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002031949,0.0003727636,0.000137408,0.0001547991,0.0001002872,0.0002276729,0.0001653865,0.0002139698,0.001050376],"category_scores_gemma":[0.0003259261,0.0001869935,0.0001983366,0.0001876088,0.0001460817,0.0002951867,0.0001492456,0.0003655536,0.0002606276],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001247606,"about_ca_system_score_gemma":0.0001155721,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004530317,"about_ca_topic_score_gemma":0.00114628,"domain_scores_codex":[0.9998505,0.00001750965,0.00001061579,0.00003691492,0.00004770549,0.000036769],"domain_scores_gemma":[0.9997469,0.00006258164,0.00009238556,0.00001984433,0.00004350243,0.00003483568],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000556228,0.00001041492,0.0001570633,0.00003770762,0.000004926364,0.00003160286,0.0000159739,0.0001026999,0.9988751,0.00001856168,0.000007349464,0.0006829959],"study_design_scores_gemma":[0.000003774481,0.0002452582,0.004194652,0.000005472467,0.00001291921,0.00007347843,0.00001887923,0.0003588461,0.9946005,0.000007158821,0.000473482,0.000005482309],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976665,0.0007930979,0.0005028609,0.00001241146,0.000008212227,0.0000116336,0.0001053938,0.00001817452,0.0008817916],"genre_scores_gemma":[0.9978782,0.0006542447,0.0006551022,0.000013547,0.000004588439,0.00001023625,0.0001037298,0.0000160262,0.0006642975],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001050376,"threshold_uncertainty_score":0.003513873,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005519550230488724,"score_gpt":0.1903291126830234,"score_spread":0.1848095624525347,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}