{"id":"W2119239517","doi":"10.1002/anie.201301881","title":"Isomerization Polymerization of the Phosphaalkene MesPCPh<sub>2</sub>: An Alternative Microstructure for Poly(methylenephosphine)s","year":2013,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Isomerization; Polymerization; Moiety; Tetrahydrothiophene; Chemistry; Photochemistry; Polymer chemistry; Stereochemistry; Crystallography; Catalysis; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000383593,0.0001646154,0.00004700731,0.00008975582,0.0000795812,0.000288784,0.0001155907,0.0001648688,0.001771329],"category_scores_gemma":[0.00005414378,0.0001125562,0.00006706237,0.0000745681,0.0001251087,0.0002024824,0.0001377984,0.0002665117,0.0003766954],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001783582,"about_ca_system_score_gemma":0.0001056733,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000164066,"about_ca_topic_score_gemma":0.0004469312,"domain_scores_codex":[0.9999694,0.000002818008,0.000001761965,0.00001137808,0.000008540022,0.000006028935],"domain_scores_gemma":[0.9999768,0.000003383074,0.000007004365,0.000003666937,0.00000323783,0.000005901406],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001805773,0.000007063792,0.00003039532,0.00001741513,0.000001259641,0.0000401998,0.00001182701,0.0001583861,0.996537,0.0009145948,0.00005338204,0.002210436],"study_design_scores_gemma":[0.000006735941,0.00008436014,0.0005275936,0.000001662524,0.000002948552,0.0001220872,0.00001070574,0.001029718,0.9948685,0.000133111,0.003209415,0.000003100645],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9676136,0.0005862179,0.01558195,0.0001181632,0.00005164415,0.00003712803,0.0002397615,0.0003101023,0.01546142],"genre_scores_gemma":[0.9888965,0.000234587,0.006387079,0.00002562387,0.000008655024,0.00001551058,0.00006467392,0.00001997581,0.00434752],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001771329,"threshold_uncertainty_score":0.005925715,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008432144525147862,"score_gpt":0.220417937439487,"score_spread":0.2119857929143391,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}