{"id":"W2119350336","doi":"10.1002/0471264180.os070.01","title":"Synthesis of <scp>N</scp> ‐Protected α‐Amino Acids from N‐(Benzyloxycarbonyl)‐ <scp>L</scp> ‐Serine via its β‐Lactone: N <sup>α</sup> ‐(Benzyloxycarbonyl)‐β‐(Pyrazol‐1‐yl)‐ <scp>L</scp> ‐Alanine","year":2003,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Serine; Alanine; Stereochemistry; Amino acid; Biochemistry; Phosphorylation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009959906,0.0004748665,0.00015084,0.0001799599,0.0001609281,0.0001912828,0.0002583599,0.0001895775,0.001982891],"category_scores_gemma":[0.0001324768,0.0001169298,0.0001754874,0.0001782426,0.0001586347,0.0002563269,0.0001823498,0.000351134,0.0008986775],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005150786,"about_ca_system_score_gemma":0.0006453263,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008489823,"about_ca_topic_score_gemma":0.001188771,"domain_scores_codex":[0.9999368,0.000007823904,0.000006764719,0.000009704514,0.00001956134,0.00001936415],"domain_scores_gemma":[0.999895,0.0000137294,0.00003528955,0.00001121079,0.00001476707,0.00003006211],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001435103,0.00002773362,0.0001053936,0.000137624,0.000008514013,0.0002789845,0.00003675282,0.0003460296,0.994091,0.0004152677,0.0002078864,0.00420132],"study_design_scores_gemma":[0.00002202809,0.000170883,0.0005177301,0.000006029944,0.000005866967,0.0001751255,0.00001303551,0.0002720437,0.9948761,0.00004878578,0.003887506,0.000004879366],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9692466,0.001400604,0.01189718,0.0001922363,0.00008315012,0.0001351314,0.00115486,0.0002126014,0.01567766],"genre_scores_gemma":[0.9787549,0.001209654,0.008776543,0.00006072192,0.00001278976,0.00007908922,0.001131891,0.00005717296,0.009917211],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001982891,"threshold_uncertainty_score":0.006633461,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008149723202515698,"score_gpt":0.2087796547302087,"score_spread":0.200629931527693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}