{"id":"W2119397353","doi":"10.1016/s1386-1425(01)00436-x","title":"A new approach to determining the geometry of weakly coupled radical pairs from their electron spin polarization patterns","year":2001,"lang":"en","type":"article","venue":"Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":false,"ca_institutions":"Brock University","funders":"Universität Stuttgart; Ontario Innovation Trust","keywords":"Spectral line; Electron paramagnetic resonance; Scaling; Dipole; Anisotropy; Singlet state; Geometry; Spectrum (functional analysis); Polarization (electrochemistry); Physics; Coupling constant; Amplitude; Chemistry; Computational physics; Molecular physics; Atomic physics; Mathematics; Nuclear magnetic resonance; Quantum mechanics; Excited state; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001715474,0.0006283944,0.0006679264,0.0001366242,0.0002739915,0.0001350658,0.0006465714,0.0002451297,0.0001969213],"category_scores_gemma":[0.00007651491,0.0005056122,0.0003131036,0.0006117826,0.0001402289,0.00009219918,0.0001644791,0.0005574971,0.000006136751],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001149494,"about_ca_system_score_gemma":0.0001495821,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002186551,"about_ca_topic_score_gemma":0.00003220573,"domain_scores_codex":[0.9968302,0.00007344651,0.0005849936,0.0009974684,0.0005347512,0.0009791416],"domain_scores_gemma":[0.99853,0.00006019787,0.0001709044,0.000812824,0.0000663759,0.0003596701],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003800004,0.000234876,0.002369768,0.00005168614,0.0003863568,0.000018064,0.0002718536,0.000002126839,0.9956645,0.0002420324,0.0001942802,0.0001844101],"study_design_scores_gemma":[0.001162596,0.000225978,0.001318961,0.00008002735,0.0002109435,0.00005346931,0.0001649458,0.0002900085,0.994181,0.0004422625,0.001314589,0.0005551918],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9307859,0.0005832085,0.06451908,0.0009383013,0.00004557113,0.0003683728,0.00006510677,0.0001108399,0.002583614],"genre_scores_gemma":[0.9962591,0.0003197687,0.002251129,0.0004063798,0.0002337025,0.00005826976,0.0002872937,0.00008004569,0.0001043265],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06547318,"threshold_uncertainty_score":0.9997395,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008680377894134143,"score_gpt":0.2380797233458329,"score_spread":0.2293993454516988,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}