{"id":"W2120016666","doi":"10.1039/b513531a","title":"Neutral and cationic aluminium complexes of a sterically demanding N-imidoylamidine ligand","year":2006,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; Bayer Canada; Ministerio de Economía y Competitividad","keywords":"Steric effects; Cationic polymerization; Chemistry; Ligand (biochemistry); Thermal decomposition; Decomposition; Medicinal chemistry; Aluminium; Stereochemistry; Crystallography; Polymer chemistry; Receptor; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002864054,0.0003490431,0.0002416278,0.0001428799,0.0001451343,0.0002968342,0.0006839627,0.0003766684,0.001887716],"category_scores_gemma":[0.0002438663,0.0001384642,0.0001426382,0.0001317087,0.0002462847,0.0002255914,0.0003446539,0.0003168979,0.0004709438],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005699706,"about_ca_system_score_gemma":0.0001513252,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000675473,"about_ca_topic_score_gemma":0.0006578988,"domain_scores_codex":[0.9998276,0.00003414912,0.00001186832,0.00003604727,0.00003987459,0.00005034309],"domain_scores_gemma":[0.9999033,0.00001772572,0.00002156791,0.0000105921,0.00001763702,0.00002908519],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005785341,0.00003618626,0.000101962,0.0001973062,0.0000118403,0.00007845537,0.00004705224,0.0003675839,0.9943383,0.001185045,0.0001935667,0.002864127],"study_design_scores_gemma":[0.0001110449,0.0005369292,0.0004806115,0.00001294252,0.00001926495,0.0001768402,0.00002445755,0.001788998,0.989282,0.0001136139,0.007436712,0.00001662895],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9814368,0.001408221,0.006078625,0.0001014181,0.00005060547,0.00006628444,0.0002973872,0.000237929,0.01032271],"genre_scores_gemma":[0.9894602,0.0004461492,0.004466443,0.00005378154,0.00001162289,0.00004269717,0.0002710157,0.00002716252,0.005220833],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001887716,"threshold_uncertainty_score":0.006314993,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01204611242617626,"score_gpt":0.2199367633157323,"score_spread":0.207890650889556,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}