{"id":"W2120032761","doi":"10.1039/b411646a","title":"Phosphonium ionic liquids as reaction media for strong bases","year":2004,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":112,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Phosphonium; Ionic liquid; Bromide; Phenylmagnesium bromide; Chemistry; Chloride; Ionic bonding; Inorganic chemistry; Organic chemistry; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000111727,0.0001674339,0.0001772417,0.00003611328,0.0002660363,0.00003110843,0.0008513061,0.0001485811,0.00005131263],"category_scores_gemma":[0.0003799618,0.0001632043,0.0001444343,0.0002123891,0.0001656475,0.0001441841,0.0002603438,0.0003378378,0.0001441268],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002909844,"about_ca_system_score_gemma":0.0001127585,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000141314,"about_ca_topic_score_gemma":0.00001077489,"domain_scores_codex":[0.9989437,0.0000112203,0.0003459312,0.0002504965,0.0001415399,0.0003071397],"domain_scores_gemma":[0.997907,0.0003316352,0.00007204239,0.001405772,0.0001428894,0.0001406774],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000322038,0.0002292173,0.000001610756,0.00002664026,0.00003003964,1.195157e-7,0.0002109023,0.00023151,0.7737119,0.2236315,0.0004572023,0.001437226],"study_design_scores_gemma":[0.0008979659,0.00003980717,0.000005556686,0.0000682232,0.00004981965,0.000009009947,0.0002296098,0.003922395,0.9104928,0.006270082,0.07771932,0.0002954004],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8190854,0.005155137,0.07220207,0.05222673,0.0006370161,0.002780471,0.0003445888,0.002534787,0.04503375],"genre_scores_gemma":[0.9824843,0.0002077031,0.01507778,0.000267285,0.0001577288,0.0007724299,0.0004125622,0.00004575515,0.0005744944],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2173614,"threshold_uncertainty_score":0.6655276,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03843521749819179,"score_gpt":0.285958371241992,"score_spread":0.2475231537438002,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}