{"id":"W2120064231","doi":"10.1002/cphc.200800406","title":"Influence of Ions on Aqueous Acid–Base Reactions","year":2009,"lang":"en","type":"article","venue":"ChemPhysChem","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Nederlandse Organisatie voor Wetenschappelijk Onderzoek","keywords":"Chemistry; Proton; Aqueous solution; Deuterium; Dissociation (chemistry); Photochemistry; Ion; Inorganic chemistry; Base (topology); Kinetic isotope effect; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006091125,0.0005775636,0.0005996879,0.0001565869,0.0002013867,0.0006081373,0.0005652097,0.0005136565,0.002178411],"category_scores_gemma":[0.001570169,0.0002588017,0.0002472173,0.0001691723,0.0004663461,0.0007221802,0.0004735222,0.0007046699,0.0005923042],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003229755,"about_ca_system_score_gemma":0.0003067162,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009304291,"about_ca_topic_score_gemma":0.0005636307,"domain_scores_codex":[0.9993641,0.0001052514,0.00006337374,0.0001220103,0.0002549279,0.0000903266],"domain_scores_gemma":[0.9988375,0.0006376469,0.0001825893,0.00006022585,0.0001980183,0.00008411695],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004967508,0.00002713478,0.0003752537,0.0001508462,0.00002070938,0.0001210481,0.00009742381,0.0004270565,0.9948918,0.0001170666,0.00005646589,0.003218462],"study_design_scores_gemma":[0.00001493661,0.0001884411,0.0002817612,0.000004190173,0.00000984928,0.00004045763,0.00001633985,0.0007049214,0.9981061,0.00004471065,0.0005825238,0.000005619802],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918253,0.002468584,0.002627238,0.0001815781,0.00009259377,0.00005861705,0.0002714527,0.0001054022,0.002369197],"genre_scores_gemma":[0.9922942,0.001725005,0.003765334,0.000107333,0.00003734708,0.00003014717,0.0002323,0.00004909027,0.001759163],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002178411,"threshold_uncertainty_score":0.007287502,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01115802901504445,"score_gpt":0.2635307117415459,"score_spread":0.2523726827265014,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}