{"id":"W2120340355","doi":"10.1016/j.tetlet.2005.10.123","title":"Catalytic oxidations of alcohols to carbonyl compounds by oxygen under solvent-free and transition-metal-free conditions","year":2005,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":100,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Ministerio de Educación, Cultura y Deporte; Canada Research Chairs; Eli Lilly and Company","keywords":"Hypervalent molecule; Chemistry; Catalysis; Reagent; Iodine; Alcohol oxidation; Transition metal; Benzene; Organic chemistry; Solvent; Styrene; Oxygen","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003370552,0.000367877,0.0002746081,0.0002269226,0.0002503139,0.0003042195,0.0004757534,0.0003130749,0.0009151332],"category_scores_gemma":[0.0003424715,0.0001358094,0.0002206261,0.0002098451,0.0003627455,0.0003933749,0.0002924234,0.0003411448,0.0001770764],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003369962,"about_ca_system_score_gemma":0.0001447573,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009895364,"about_ca_topic_score_gemma":0.00194834,"domain_scores_codex":[0.9997484,0.00002886715,0.00001543739,0.00003255745,0.00007845497,0.00009623382],"domain_scores_gemma":[0.9999191,0.00002148215,0.00001877119,0.00001368973,0.00001286811,0.00001419193],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001253505,0.0000717118,0.000463905,0.0002281145,0.00003289919,0.0001938279,0.0001904808,0.000288728,0.9867553,0.001285524,0.0004342273,0.008801771],"study_design_scores_gemma":[0.00004152827,0.0001730868,0.0005967665,0.000004413279,0.00001765174,0.00007167365,0.00003615572,0.0005145237,0.9969092,0.0001122848,0.001515449,0.000007227971],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938425,0.0009311006,0.002038014,0.00007705216,0.00005674252,0.00001480574,0.0001021469,0.00005456692,0.002883148],"genre_scores_gemma":[0.9982237,0.0004759824,0.000383174,0.00001301675,0.00001307647,0.000004124186,0.0001160254,0.000008651094,0.0007622095],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009895364,"threshold_uncertainty_score":0.003061473,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009749912787199704,"score_gpt":0.2358804677187975,"score_spread":0.2261305549315978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}