{"id":"W2120347291","doi":"10.1021/jp011962a","title":"High-Field Chlorine NMR Spectroscopy of Solid Organic Hydrochloride Salts:  A Sensitive Probe of Hydrogen Bonding Environment","year":2001,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":96,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Hydrochloride; Chlorine; Chloride; Magic angle spinning; Hydrogen chloride; Nuclear magnetic resonance spectroscopy; Quinuclidine; Analytical Chemistry (journal); Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001226234,0.000178757,0.0004166602,0.00001461759,0.00005342493,0.00000327941,0.0003346307,0.00006665011,0.00020232],"category_scores_gemma":[0.00004948513,0.0001335211,0.0001769004,0.0001327016,0.0001232881,0.00006815707,0.0001031766,0.0004105421,0.000002856476],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009654396,"about_ca_system_score_gemma":0.00003744174,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000737673,"about_ca_topic_score_gemma":1.932823e-7,"domain_scores_codex":[0.9988497,0.000009072668,0.0004845842,0.0001331773,0.0003147679,0.0002086866],"domain_scores_gemma":[0.9985375,0.0001808388,0.0007606896,0.000362279,0.00006942782,0.00008921599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002036424,0.0003105904,0.00001139639,0.00008150637,0.00007863466,0.000008486348,0.0001687167,0.001159559,0.99771,0.0001138041,0.0000421426,0.000111492],"study_design_scores_gemma":[0.000342387,0.000112223,0.000005857012,0.000140162,0.0001251521,0.0001149133,0.000173696,0.0005531058,0.9940171,0.003933831,0.0003629061,0.0001186645],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903968,0.00004643342,0.008137709,0.0003540497,0.000002199454,0.00006309533,0.00002089739,0.00001773828,0.0009610565],"genre_scores_gemma":[0.998301,0.0001586661,0.0007289952,0.00002196836,0.0004892309,0.000005143174,0.000004131232,0.00002418901,0.0002666543],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007904201,"threshold_uncertainty_score":0.5444832,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007375415663664833,"score_gpt":0.2541506511868066,"score_spread":0.2467752355231418,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}