{"id":"W2120580595","doi":"10.1139/v10-157","title":"Pseurotin A<sub>1</sub> and A<sub>2</sub>, two new 1-oxa-7-azaspiro[4.4]non-2-ene-4,6-diones from the holothurian-derived fungus <i>Aspergillus fumigatus</i> WFZ-25","year":2011,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Aspergillus fumigatus; Fungus; Ene reaction; Stereochemistry; Circular dichroism; Aspergillus; D-Glucopyranose; Botany","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005701258,0.0005174236,0.0002067721,0.0003476852,0.0001304174,0.0002490859,0.0001480516,0.0002239455,0.0008206375],"category_scores_gemma":[0.00008214007,0.0001203077,0.0002197463,0.0002467746,0.0001721669,0.0002506449,0.0001817666,0.000304042,0.0002901965],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002135603,"about_ca_system_score_gemma":0.0003737543,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001010892,"about_ca_topic_score_gemma":0.002906345,"domain_scores_codex":[0.9999511,0.000007568406,0.000005230985,0.00001023804,0.00001436174,0.00001146626],"domain_scores_gemma":[0.9999435,0.000004826341,0.00001309333,0.000004816868,0.000008825281,0.00002487017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001675335,0.00002140861,0.0003890189,0.00008231285,0.00001111443,0.0001660808,0.00002163069,0.0001739382,0.9946492,0.000104227,0.00004828099,0.004165261],"study_design_scores_gemma":[0.00005028553,0.0009799263,0.01338286,0.00001651552,0.00004370129,0.0007423752,0.00008452065,0.0003309297,0.9747512,0.0001769031,0.009420301,0.00002046403],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865414,0.004589294,0.00355979,0.00008196712,0.00005161503,0.000114754,0.001303974,0.00007585969,0.003681273],"genre_scores_gemma":[0.9859998,0.002190213,0.00606799,0.0001162807,0.00001390121,0.00005001618,0.002223257,0.00001120807,0.003327325],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001010892,"threshold_uncertainty_score":0.00274533,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01406480712334806,"score_gpt":0.1937950945155767,"score_spread":0.1797302873922286,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}