{"id":"W2120770658","doi":"10.1139/v00-014","title":"Synthesis and reactivity of the stable silylene <i>N</i>,<i>N</i>'-di-<i>tert-</i>butyl-1,3-diaza-2-sila-2-ylidene","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Science Foundation","keywords":"Silylene; Chemistry; Reactivity (psychology); Carbene; Medicinal chemistry; Derivative (finance); Stereochemistry; Organic chemistry; Catalysis; Silicon","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001062552,0.0002331061,0.0001059479,0.000109323,0.0001673876,0.0001800689,0.0002087051,0.0001621475,0.001272936],"category_scores_gemma":[0.00009763586,0.00009593641,0.00009249616,0.0001028813,0.0001420838,0.0002033603,0.0001052154,0.0001816923,0.0003081709],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003434755,"about_ca_system_score_gemma":0.0002254441,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007202615,"about_ca_topic_score_gemma":0.001858446,"domain_scores_codex":[0.9999422,0.000004559617,0.000003037789,0.00001589685,0.00001846768,0.00001587676],"domain_scores_gemma":[0.999945,0.000006725496,0.00001535851,0.000005390387,0.000008990582,0.000018468],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003443614,0.00001909388,0.0001203804,0.00004442309,0.00000335306,0.00006071181,0.00002686773,0.0001704565,0.9955651,0.0003694201,0.00006367703,0.00352215],"study_design_scores_gemma":[0.000005869293,0.0001729116,0.000504034,0.000001766564,0.000004117612,0.00009062006,0.000007754778,0.0002138723,0.995901,0.00003118304,0.003063172,0.000003655218],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9859935,0.001592055,0.004081979,0.0000577073,0.00001702847,0.00004900433,0.0002623101,0.00004946372,0.00789695],"genre_scores_gemma":[0.9878713,0.001155308,0.005118711,0.00003095057,0.000006437767,0.00002540268,0.0004279442,0.00002234662,0.005341532],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001272936,"threshold_uncertainty_score":0.004258454,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008233678240034684,"score_gpt":0.1798090877355018,"score_spread":0.1715754094954672,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}