{"id":"W2120877342","doi":"10.1139/v2012-012","title":"Ring-opening polymerization of <i>rac</i>-lactide and ε-caprolactone using zinc and calcium salicylaldiminato complexes","year":2012,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; University of Prince Edward Island","funders":"Natural Sciences and Engineering Research Council of Canada; Atlantic Canada Opportunities Agency","keywords":"Chemistry; Polymerization; Polymer chemistry; Lactide; Ring-opening polymerization; Caprolactone; Zinc; Ligand (biochemistry); Disproportionation; Imine; Catalysis; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001903356,0.000424904,0.0002420343,0.0001587862,0.0000971081,0.0002605275,0.0003374846,0.0002283431,0.0006070177],"category_scores_gemma":[0.0002088051,0.0001944915,0.0002348394,0.0001337569,0.0001831642,0.0002057516,0.000206487,0.0002632368,0.0002233691],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004624636,"about_ca_system_score_gemma":0.000187273,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000390551,"about_ca_topic_score_gemma":0.0005959802,"domain_scores_codex":[0.9998167,0.00002344662,0.00001594298,0.00004492263,0.00005051462,0.00004844207],"domain_scores_gemma":[0.9998386,0.00002041929,0.00007152054,0.00001145498,0.00002122624,0.00003680179],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004570531,0.00001084383,0.00004328113,0.00002784565,0.000003342738,0.00002582961,0.00001115525,0.0001285805,0.998714,0.00008562263,0.00001310828,0.0008907499],"study_design_scores_gemma":[0.000006308089,0.00007757147,0.0001562468,0.000001055078,0.000003472403,0.00003072882,0.00000297977,0.0002985835,0.9989848,0.000007658475,0.0004281857,0.000002407297],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905475,0.0009224467,0.005223406,0.00005226272,0.00002237481,0.00004454582,0.00006696245,0.000146729,0.002973928],"genre_scores_gemma":[0.9924925,0.0004004962,0.004618647,0.00003063064,0.000007529325,0.00002490693,0.0000875726,0.00003038696,0.002307424],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006070177,"threshold_uncertainty_score":0.003355384,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03501783005554501,"score_gpt":0.2408431453547857,"score_spread":0.2058253152992407,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}