{"id":"W2121029205","doi":"10.1002/anie.200803611","title":"Secondary Alkyl Halides in Transition‐Metal‐Catalyzed Cross‐Coupling Reactions","year":2009,"lang":"en","type":"review","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":814,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Halide; Alkyl; Electrophile; Chemistry; Coupling reaction; Catalysis; Beta-Hydride elimination; Coupling (piping); Transition metal; Photochemistry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003890258,0.0007410147,0.001235336,0.0006287218,0.0002322569,0.0003985758,0.0006716439,0.0008573098,0.003571432],"category_scores_gemma":[0.0003574853,0.0008158805,0.001001155,0.000482722,0.0002079985,0.0008959231,0.00008532729,0.001559708,0.0002666033],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001575061,"about_ca_system_score_gemma":0.0004818763,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002626802,"about_ca_topic_score_gemma":0.00008884525,"domain_scores_codex":[0.9961678,0.000002781893,0.001586883,0.001028749,0.0007156252,0.0004981727],"domain_scores_gemma":[0.9975932,0.0004491212,0.0008011662,0.0006669099,0.0003214486,0.0001682072],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0003625398,0.004543821,0.00004296762,0.04399202,0.004299248,0.001108474,0.001333896,0.001496764,0.1565673,0.001099306,0.02058768,0.764566],"study_design_scores_gemma":[0.0009261376,0.000008811858,0.000009668969,0.01024832,0.0005249832,0.0005122821,0.00007450117,0.0001240415,0.1176861,0.0005904449,0.8684019,0.0008927741],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.002433807,0.972383,0.0003286176,0.0003674008,0.003437971,0.0005449476,0.003707384,0.0006231094,0.01617374],"genre_scores_gemma":[0.00625398,0.9535806,0.00006306921,0.00005875235,0.004417691,0.0003939984,0.03219212,0.0001515079,0.002888293],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.8478142,"threshold_uncertainty_score":0.9994292,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03410966044295258,"score_gpt":0.3414204809876765,"score_spread":0.3073108205447239,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}