{"id":"W2121151545","doi":"10.1002/anie.200704711","title":"Enamide Synthesis by Copper‐Catalyzed Cross‐Coupling of Amides and Potassium Alkenyltrifluoroborate Salts","year":2008,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":150,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Halide; Potassium; Chemistry; Catalysis; Copper; Coupling (piping); Combinatorial chemistry; Organic chemistry; Medicinal chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002598656,0.0007391559,0.0003100176,0.0002642847,0.0002480177,0.0003344045,0.0003902886,0.000341633,0.002006325],"category_scores_gemma":[0.0001804976,0.0002778449,0.0002501951,0.0002025209,0.000231652,0.0004889931,0.000404831,0.0004754723,0.001060678],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003084521,"about_ca_system_score_gemma":0.0003334844,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005445495,"about_ca_topic_score_gemma":0.0009686231,"domain_scores_codex":[0.9998382,0.00001604806,0.0000248371,0.00004459577,0.00003667666,0.00003960231],"domain_scores_gemma":[0.9999274,0.000005480066,0.00001783344,0.0000151412,0.00001634255,0.00001777815],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006276672,0.00003773612,0.00006801966,0.0001465019,0.00001428448,0.0002415113,0.00004090654,0.0001931521,0.9907617,0.0007261421,0.0001675656,0.007539707],"study_design_scores_gemma":[0.00001520311,0.0001186952,0.0001742511,0.000005066749,0.000008662811,0.0002122229,0.00000559954,0.0001306086,0.9940335,0.00004912016,0.005240966,0.000006176094],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8860837,0.006215228,0.06442287,0.0002751079,0.0004084862,0.0004712237,0.000998662,0.001156275,0.03996835],"genre_scores_gemma":[0.9513314,0.004625208,0.02993645,0.00006085007,0.00004005637,0.0001582658,0.000667598,0.000129823,0.01305043],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002006325,"threshold_uncertainty_score":0.006711841,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01007685092688852,"score_gpt":0.2449072534674652,"score_spread":0.2348304025405767,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}