{"id":"W2121573804","doi":"10.1002/anie.201402567","title":"Boron Perturbed Click Reactions Prompt Aromatic CH Activations","year":2014,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Boron; Toluene; Chemistry; Benzene; Phosphonium; Adduct; Medicinal chemistry; Deprotonation; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002276336,0.000400965,0.0001860332,0.0002065609,0.000216399,0.0002980613,0.0002479978,0.0004653945,0.008105372],"category_scores_gemma":[0.0003575207,0.0001771749,0.000214745,0.0001911965,0.0002472076,0.000641447,0.0005609686,0.0006756464,0.001488142],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000328855,"about_ca_system_score_gemma":0.0002056547,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003989837,"about_ca_topic_score_gemma":0.0008480383,"domain_scores_codex":[0.9997277,0.0000214428,0.00001305009,0.00004699452,0.00005730537,0.0001334165],"domain_scores_gemma":[0.9998802,0.0000276599,0.0000211623,0.0000205203,0.00001670722,0.00003374754],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004560258,0.00005030337,0.0003118992,0.00009387499,0.0000120368,0.0005955368,0.00007995428,0.000377823,0.9827195,0.00553349,0.0009948392,0.008774554],"study_design_scores_gemma":[0.00002817789,0.0001984877,0.0006454905,0.000005171254,0.000004562711,0.0003105134,0.00001957187,0.0005556869,0.9934531,0.00051057,0.004256838,0.000011747],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9441746,0.001233906,0.01619628,0.0003850114,0.0002332014,0.0001060992,0.001076668,0.0009601947,0.035634],"genre_scores_gemma":[0.9925849,0.0003285379,0.001346457,0.00005487913,0.00001388905,0.00001625433,0.0002106571,0.00004052194,0.005403941],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008105372,"threshold_uncertainty_score":0.02711517,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01666964012618827,"score_gpt":0.2692337106992012,"score_spread":0.2525640705730129,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}