{"id":"W2121843122","doi":"10.1007/s10904-015-0204-7","title":"CuX (X = Cl, Br, I) Containing Coordination Polymers Built Upon Isomeric RSCH2C≡CCH2SR (R = p-Tolyl, Benzyl) Dithioether Ligands: First Example of a Luminescent (CuCl)n/Dithioether Network","year":2015,"lang":"en","type":"article","venue":"Journal of Inorganic and Organometallic Polymers and Materials","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Ligand (biochemistry); Thioether; Luminescence; Chemistry; Stereochemistry; Crystallography; Coordination polymer; Crystal structure; Materials science; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001017597,0.000438464,0.001148651,0.0001840848,0.0002211086,0.0001595446,0.0003661152,0.0003380273,0.003651189],"category_scores_gemma":[0.0002503893,0.0003588381,0.0001422475,0.0004339987,0.0002408767,0.0003282616,0.000177125,0.000277581,0.000009350593],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008134053,"about_ca_system_score_gemma":0.0001980018,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005803828,"about_ca_topic_score_gemma":0.00003944279,"domain_scores_codex":[0.9971784,0.00008078576,0.001376244,0.0004089829,0.0004596387,0.0004959058],"domain_scores_gemma":[0.9970966,0.0002402579,0.001594553,0.0004045308,0.0002255518,0.0004385368],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003491327,0.0003024607,0.001750023,0.0002401096,0.0005740387,0.00001166965,0.001735256,0.00001034064,0.9870478,0.001707532,0.0009080755,0.005363575],"study_design_scores_gemma":[0.004020229,0.0006416627,0.003447552,0.0008000824,0.001025568,0.0004644909,0.005396611,0.00006883621,0.9593156,0.0008016963,0.02294531,0.001072367],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9866237,0.01070012,0.0008096866,0.0007281657,0.000526743,0.0001648522,0.0000490456,0.000031277,0.0003663972],"genre_scores_gemma":[0.9952492,0.002467783,0.0005791638,0.000170958,0.000806897,0.00001090004,0.00001647717,0.00009291515,0.0006057505],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02773219,"threshold_uncertainty_score":0.9998863,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02374388788748628,"score_gpt":0.2412221406154524,"score_spread":0.2174782527279661,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}